77084-80-1Relevant academic research and scientific papers
Studies on the regio- and stereoselectivity of halohydroxylation of 1,2-allenyl sulfides or selenides
Ma, Shengming,Hao, Xueshi,Meng, Xiaofeng,Huang, Xian
, p. 5720 - 5724 (2007/10/03)
It was observed that the halohydroxylation of 1,2-allenyl sulfides or selenides with Br2 (CuBr2 or NBS) or I2 and water demonstrated a fairly good regioselectivity (i.e., the C=C bond that is remote from the S or Se atom w
PHENYLTHIOCOPPER TRIMETHYLPHOSPHITE COMPLEX. A REAGENT FOR THE PREPARATION OF THIOALLENES.
Bridges, Alexander J.
, p. 4401 - 4404 (2007/10/02)
The title complex reacts with propargyl halides and, in situ generated, propargyl mesylates to produce thioallenes in good yields, via an allylic inversion.
