77084-83-4Relevant academic research and scientific papers
Gold-Catalyzed Oxidative Hydrative Alkenylations of Propargyl Aryl Thioethers with Quinoline N-Oxides Involving a 1,3-Sulfur Migration
Wagh, Sachin Bhausaheb,Singh, Rahulkumar Rajmani,Sahani, Rajkumar Lalji,Liu, Rai-Shung
, p. 2755 - 2758 (2019/04/30)
This work reports gold-catalyzed oxidative alkenylations of quinoline N-oxides with propargyl aryl thioethers to afford 3-hydroxy-1-alkylidenephenylthiopropan-2-one via a 1,3-sulfur group migration. The mechanism of this reaction is postulated to involve
LEAVING GROUP DEPENDENT STEREOCHEMISTRY OF THIOALLENE FORMATION WITH PHENYLTHIOCOPPER PHOSPHINE COMPLEXES
Bridges, Alexander J.,Ross, Robert J.
, p. 4797 - 4800 (2007/10/02)
A Chiral secondary propargylic triflate (5) reacts with phenylthiocopper phosphine complexes (1) and (2) to give propargyl and allenic sulphides with complete inversion of configuration, but the corresponding mesylate (4) reacts with both complexes to give racemic products.
