77102-55-7 Usage
Substituted benzene molecule
1-methyl-3-(prop-2-en-1-ylsulfanyl)benzene is derived from a benzene molecule by replacing one hydrogen atom with a methyl group and another with a propenylsulfanyl group.
Methyl group at the first position
The methyl group (CH3) is attached to the benzene ring at the first position, which is one of the six positions available around the ring.
Propenylsulfanyl (allylthio) group at the third position
The propenylsulfanyl group (CH2=CH-CH2S) is attached to the benzene ring at the third position, giving the compound its unique properties.
Common use in organic synthesis
1-methyl-3-(prop-2-en-1-ylsulfanyl)benzene is frequently used as an intermediate in the synthesis of more complex organic compounds.
Presence in aromatic compounds
This chemical compound can be found in various aromatic compounds, which are characterized by their benzene-like structure and stability.
Strong and pungent odor
1-methyl-3-(prop-2-en-1-ylsulfanyl)benzene is known for its intense and pungent smell, which may be unpleasant or irritating.
Applications in fragrances, pharmaceuticals, and other chemical products
The compound is used in the production of various consumer products, including fragrances, pharmaceuticals, and other chemical goods.
Importance of safety measures
Due to potential hazards, it is crucial to handle 1-methyl-3-(prop-2-en-1-ylsulfanyl)benzene with caution and follow appropriate safety guidelines to prevent harm.
Check Digit Verification of cas no
The CAS Registry Mumber 77102-55-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,1,0 and 2 respectively; the second part has 2 digits, 5 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 77102-55:
(7*7)+(6*7)+(5*1)+(4*0)+(3*2)+(2*5)+(1*5)=117
117 % 10 = 7
So 77102-55-7 is a valid CAS Registry Number.
77102-55-7Relevant academic research and scientific papers
Yb(iii)-catalysedsyn-thioallylation of ynamides
Dutta, Shubham,Gandon, Vincent,Gogoi, Manash Protim,Mallick, Rajendra K.,Prabagar, B.,Sahoo, Akhila K.,Vanjari, Rajeshwer,Yang, Shengwen
supporting information, p. 7521 - 7524 (2021/08/05)
Reported herein is asyn-thioallylation of ynamides incorporating a sulfide moiety at the α-position and an allyl group at the β-position of the ynamide. The transformation is successful under ytterbium(iii)-catalysis, providing access to highly substituted thioamino-skipped-dienes with broad substrate scope. Thus, tetrasubstituted olefins (with four different functional groups: amide, phenyl, thioaryl/alkyl, and allyl on the carbon centers) are made in a single step from readily accessible ynamides, preserving complete atom economy. The reaction can be extended to the synthesis of selenoamino dienes by ynamidesyn-selenoallylation. DFT studies and control experiments provide insight into the reaction mechanism.
Aqueous hemin catalyzed sulfonium ylide formation and subsequent [2,3]-sigmatropic rearrangements
Xu, Xiaofei,Li, Chang,Tao, Zhihao,Pan, Yuanjiang
supporting information, p. 1245 - 1249 (2017/08/15)
A mild hemin catalytic system for sulfonium ylide generation via a metal carbenoid and a subsequent [2,3]-sigmatropic rearrangement reaction in aqueous solvent is well-established, with the assistance of cyclodextrin (CD) and Triton X-100. The protocol displays high catalytic activity with a broad substrate scope of aryl/alkyl allyl sulfides and diazo reagents, affording homoallyl sulfide products in up to 99% yield. Notably, this catalytic system is successful for water-insoluble allyl sulfides but ineffective for allyl amines or allyl ethers. Moreover, an unprecedented cascade reaction of sulfonium ylide formation, [2,3]-sigmatropic rearrangement and C-H insertion was reported.
