77102-70-6Relevant academic research and scientific papers
Electrochemical Reduction of Diaryl Trithiocarbonates and Related Compounds
Falsig, M.,Lund, H.,Nadjo, L.,Saveant, J. M.
, p. 685 - 692 (2007/10/02)
Electrochemical reduction of diaryl trithiocarbonates (1) in aprotic medium followed by alkylation gives a mixture of Z- ad E-tetrathioethylenes (2) and thioanisoles (3) in which Z:E ratio is approximately 1:10.The influence of different parameters on the yield of 2 and 3 has been investigated, and these results together with those from a kinetic investigation published elsewhere have been used in a discussion of the reaction mechanism.
Electrochemical Reduction of Alkyl Aryl and Dialkyl Trithiocarbonates
Falsig, Mogens,Lund, Henning
, p. 545 - 550 (2007/10/02)
Electrochemical reduction in aprotic medium of alkyl aryl trithiocarbonates (1a-c) in the presence of an alkylating agent gives tetraalkyltetrathioethylenes (2a-c); under similar conditions dialkyl trithiocarbonates (3a-c) also form 2, but the reaction is complicated by the ability of 3 to act as an alkylating agent.The mechanisms of the reactions are discussed on the basis of the preparative and cyclic voltammetric results.
