2314-54-7

Basic information

• Product Name: Di(phenylthio)methanethione
• Synonyms: Di(phenylthio)methanethione;Trithiocarbonic acid diphenyl ester
• CAS NO: 2314-54-7
• Molecular Formula: C₁₃H₁₀S₃
• Molecular Weight: 262.4135
• Mol File: 2314-54-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 430.1 °C at 760 mmHg
• Flash Point: 213.9 °C
• Appearance: /
• Density: 1.31 g/cm³
• Vapor Pressure: 3.35E-07mmHg at 25°C
• Refractive Index: 1.721
• CAS DataBase Reference: Di(phenylthio)methanethione(CAS DataBase Reference)
• NIST Chemistry Reference: Di(phenylthio)methanethione(2314-54-7)
• EPA Substance Registry System: Di(phenylthio)methanethione(2314-54-7)

Safety Data

• Hazardous Substances Data: 2314-54-7(Hazardous Substances Data)

Usage

General Description

Di(phenylthio)methanethione, also known as diphenylthiomethane, is a chemical compound with the molecular formula C13H10S2. It is a sulfur-containing organic compound that is commonly used as a rubber additive and in the production of rubber products. Di(phenylthio)methanethione is known for its ability to prevent the degradation and oxidation of rubber, making it an important component in the manufacturing of tires, seals, and other rubber-based products. Additionally, it is used as a stabilizer and anti-aging agent for rubber and plastic materials. However, exposure to high concentrations of this chemical may cause skin and eye irritation, and it is important to handle it with caution in industrial and laboratory settings.

InChI:InChI=1/C13H10S3/c14-13(15-11-7-3-1-4-8-11)16-12-9-5-2-6-10-12/h1-10H

Upstream product

• 16911-89-0 phenyl chlorodithioformate 
• 930-69-8 sodium thiophenolate 
• 463-71-8 thiophosgene 
• 50900-13-5 diphenyl trithiocarbonate S-oxide 
• 108-98-5 thiophenol 
• 75-15-0 carbon disulfide 
• 17763-67-6 Phenyl triflate 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 591-50-4 iodobenzene 
• 4551-15-9 phenylthiotrimethylsilane 
• 369-57-3 benzenediazonium tetrafluoroborate 
• 594-42-3 chlorothio-trichloro-methane 
• 121-69-7 N,N-dimethyl-aniline 

Downstream Products

• 89694-42-8 S-benzyldithiocarbazate 
• 27722-60-7 1,1,2-Tris(phenylmercapto)-2-phenyl-aethen 
• 4832-52-4 tris(phenylthio)methane 
• 102971-09-5 4',4'-bis(phenylthio)spiro[adamantane-2,2'-(1,3)-dithiolane] 
• 285120-11-8 5,5-diphenyl-4,4-bis(phenylthio)-1,3-dithiolane 
• 41563-48-8 (2,2-diphenylethene-1,1-diyl)bis(phenylsulfane) 
• 24455-23-0 S₁,S₂-Diphenylethanebis(thioate) 
• 13509-36-9 S,S’-diphenyl dithiocarbonate 
• 108-98-5 thiophenol 
• 68374-33-4 E-1,2-bis(methylthio)-1,2-bis(phenylthio)ethylene 
• 100-68-5 methyl-phenyl-thioether 
• 77105-20-5 Z-1,2-bis(methylthio)-1,2-biss(phenylthio)ethylene 
• 100181-18-8 3-Phenyl-6,6-bis-phenylsulfanyl-4H-[1,5,2]oxathiazine 
• 3019-20-3 isopropylthiobenzene 

Relevant articles and documents

Investigations of the Thermal Responsiveness of 1,4,2-Oxathiazoles

The first systematic study of the thermal rearrangement/fragmentation of 5,5-disubstituted 1,4,2-oxathiazoles into isothiocyanates is reported. Structure-activity relationships reveal that the choice of substituent at the 5-position of the 1,4,2-oxathiazoles is the predominant factor to influence the ease of fragmentation.

One-pot synthesis of symmetrical diaryl trithiocarbonates through copper-catalyzed coupling of aryl compounds, sodium sulfide, and carbon disulfide

In this study, a protocol for the synthesis of symmetrical diaryl trithiocarbonates through the one-pot copper-catalyzed coupling reaction of sodium sulfide, carbon disulfide, and aryl compounds in DMF solution is presented. This method allows the synthesis of symmetrical diaryl trithiocarbonates without the use of highly toxic thiophosgene, and also, commercially available aryl halides were used instead of less available, toxic thiols.

Some Reactions of Trichloromethanesulfenyl Chloride with Alcohols and Thiols

Four new trichloromethyl disulfides, four alkyl orthocarbonates, and two trithiocarbonates have been synthesized and have been characterized by physical, spectral, and analytical properties.