77117-51-2Relevant academic research and scientific papers
Ring Reversal of cis-Cyclohexane-1,2,3,4,5,6-hexacarboxylic Acid and its Hexamethyl Ester
Gatti, Giuseppe,Grassi, Maria,Silvestro, Giuseppe Di,Farina, Mario,Brueckner, Sergio
, p. 255 - 258 (2007/10/02)
cis-Cyclohexane-1,2,3,4,5,6-hexacarboxylic acid and its hexamethyl ester have been synthesized and shown, by n.m.r. to exist in solution at room temperature as an equilibrium of slowly exchanging chair conformations.From complete line shape analysis of th
STEREOCHEMISTRY OF SUBSTITUTED BICYCLOOCTENES
Grassi, Maria,Silvestro, Giuseppe Di,Farina, Mario
, p. 341 - 346 (2007/10/02)
The epimerization of the methyl ester of 2,3,5,6-endo-bicyclo-7-octenetetracarboxylic acid produces three stereoisomers with one or two substituents in the exo position.Their structure was determined by 13C- and 1H-NMR spectroscopy and reactivity s
