77123-71-8Relevant academic research and scientific papers
Dual Nickel- And Photoredox-Catalyzed Reductive Cross-Coupling of Aryl Halides with Dichloromethane via a Radical Process
Xu, Tao,Xu, Wenhao,Zheng, Purui
supporting information, (2020/11/13)
The first catalytic strategy to harness a new chloromethane radical from dichloromethane under dual Ni/photoredox catalytic conditions has been developed. Compared with traditional two-electron reductive process associated with metallic reductants, this method via a single-electron approach can proceed under exceptionally mild conditions (visible light, ambient temperature, no strong base) and exhibits complementary reactivity patterns. It affords a broad scope of many functional groups, including alkenyl, which suffers cyclopropanation in previous routes. The diarylmethane-d2 compounds can be readily available with this transformation.
AgI-directed triple-stranded helicates with meta-ethynylpyridine ligands
Li, Qiaolian,Huang, Fu,Fan, Yaxun,Wang, Yilin,Li, Jianfeng,He, Yujian,Jiang, Hua
, p. 3235 - 3244 (2015/04/27)
A series of triple-stranded complexes, [1a3Ag]BF4, [1b3Ag]BF4, [2a3Ag2](BF4)2, [2b3Ag2](BF4)2, and [33Ag3/
AgI-directed triple-stranded helicates with meta-ethynylpyridine ligands
Li, Qiaolian,Huang, Fu,Fan, Yaxun,Wang, Yilin,Li, Jianfeng,He, Yujian,Jiang, Hua
, p. 3235 - 3244 (2014/07/22)
A series of triple-stranded complexes, [1a3Ag]BF4, [1b3Ag]BF4, [2a3Ag2](BF 4)2, [2b3Ag2](BF4) 2, and [33Ag3
Facile Synthesis of Ethynylated Benzoic Acid Derivatives and Aromatic Compounds via Ethynyltrimethylsilane
Austin, William B.,Bilow, Norman,Kelleghan, William J.,Lau, Kreisler S. Y.
, p. 2280 - 2286 (2007/10/02)
The coupling reaction between an aromatic halide and ethynyltrimethylsilane under the catalysis of palladium(0) generated in situ, followed by treatment of the (trimethylsilyl)ethynyl product with potassium carbonate in methanol at ambient temperatures, provides a simple approach to various ethynylated benzoic acid derivatives and other aromatic compounds.The conditions for the removal of the trimethylsilyl group were very mild, so that base-sensitive functionalities on the aromatic moiety could be tolerated.
