7714-62-7Relevant academic research and scientific papers
Iodine-mediated 1,2-aryl migration of primary benzhydryl amines
Chang, Junbiao,Du, Yangxu,Hao, Wei,Hou, Jiao,Lu, Qing,Yu, Wenquan
supporting information, p. 16223 - 16226 (2021/09/22)
An iodine-mediated 1,2-aryl migration reaction of primary benzhydryl amines under transition metal-free conditions has been achieved. The crude imines generated by this rearrangement reaction can be directly transformed into various aromatic secondary ami
Copper-Catalyzed Umpolung of Imines through Carbon-to-Nitrogen Boryl Migration
Li, Zhenghua,Zhang, Liang,Nishiura, Masayoshi,Hou, Zhaomin
, p. 4388 - 4393 (2019/05/08)
We report a general strategy for the catalytic umpolung of imines, which was enabled by an unprecedented 1,2-boryl carbon-to-nitrogen migration. Based on the discovery of a rearrangement of an α-borylalkylamido copper intermediate to an α-borylaminoalkyl
NOVEL CATALYSTS
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Page/Page column 66, (2012/06/01)
The present invention provides novel compounds and ligands that are useful in transition metal catalyzed cross-coupling reactions. For example, the compounds and ligands of the present invention are useful in palladium or gold catalyzed cross-coupling reactions.
Synthesis and structure of 2-aryl-2,4-dimethyl-1,2,3,4-tetrahydroquinolines and 1,3-disubstituted indenes
Zvolinskii,Kryvenko,Sergeeva,Soldatenkov,Prostakov
, p. 86 - 90 (2007/10/03)
It has been shown that the intramolecular cyclization of N-(1-arylbutenyl)arylamines under acid catalysis conditions may proceed in two directions with the formation of 2-aryl-2,4-dimethyl-1,2,3,4-tetrahydroquinolines and 1,3 disubstituted indenes. 1997 P
