77144-21-9Relevant academic research and scientific papers
Copper-Catalyzed Alkenylation of Alcohols with β-Nitrostyrenes via a Radical Addition-Elimination Process
Guo, Sheng-Rong,Yuan, Yan-Qin
supporting information, p. 1961 - 1968 (2015/09/01)
A new method for the preparation of allylic alcohol derivatives has been developed via a radical mechanism using DTBP as the radical initiator promoted by copper salt. The C(sp3)-H bond in various alcohols, toluene derivatives, and alkanes were successfully converted into C-C bonds to yield the desired products in moderate to good yields.
Enantioselective epoxidation of tertiary allylic alcohols by chiral dihydroperoxides
Bunge, Alexander,Hamann, Hans-Jürgen,Dietz, Dennis,Liebscher, Jürgen
supporting information, p. 2446 - 2450 (2013/03/14)
gem-Dihydroperoxides were successfully used for the enantioselective epoxidation of tertiary and primary allylic alcohols. Epoxides derived from tertiary alcohols were obtained in yields up to 71% with ee's up to 52%.
A stereoselective synthesis of unsaturated phosphonates by Wittig-Horner reactions of bisphosphonylmethane with 5-aryl-(3-methyl)-2E,4E-pentadienals
Shi, De Qing,Chen, Ru Yu
, p. 229 - 237 (2007/10/03)
A new type of unsaturaled phosphonates 5 were synthesized by the Wittig-Horner reactions of bisphosphonylmethane 4 with 5-aryl-2(E),4(E)-pentadienal and 5-aryl-3-methyl-2(E), 4(E)-pentadienal. The structures of all new compounds prepared were characterize
