771477-95-3

Upstream product

• 114106-93-3 methyl 2-[hydroxy(4-nitrophenyl)methyl]prop-2-enoate 

Downstream Products

• 1190078-78-4 C₁₆H₂₀NO₇P 
• 1228955-10-9 2-(3-methylbenzyl)-3-(4-nitrophenyl) acrylic acid methyl ester 
• 1228955-13-2 2-(4-fluorobenzyl)-3-(4-nitrophenyl) acrylic acid methyl ester 
• 92-52-4 biphenyl 
• 1228955-08-5 2-benzyl-3-(4-nitrophenyl) acrylic acid methyl ester 
• 1228955-09-6 2-(4-methylbenzyl)-3-(4-nitrophenyl) acrylic acid methyl ester 
• 1228955-14-3 2-(4-chlorobenzyl)-3-(4-nitrophenyl) acrylic acid methyl ester 
• 1228955-11-0 2-(4-methoxybenzyl)-3-(4-nitrophenyl) acrylic acid methyl 
• 1228955-12-1 2-(4-ethoxybenzyl)-3-(4-nitrophenyl) acrylic acid methyl ester 
• 1010833-04-1 methyl (Z)-3-(4-nitrophenyl)-2-(thiocyanomethyl)propenoate 
• 1463434-27-6 methyl (E)-3-(4-nitrophenyl)-2-[(2,3-dioxo-2,3-dihydro-1H-1-indolyl)methyl]-2-propionate 
• 1463434-28-7 methyl (E)-3-(4-nitrophenyl)-2-[(5-chloro-2,3-dioxo-2,3-dihydro-1H-1-indolyl)methyl]-2-propionate 
• 1463434-29-8 methyl (E)-3-(4-nitrophenyl)-2-[(5-fluoro-2,3-dioxo-2,3-dihydro-1H-1-indolyl)methyl]-2-propionate 
• 84782-92-3 methyl 2-(4-nitrobenzyl)acrylate 

Relevant academic research and scientific papers

Pd(0)-catalyzed couplings using bromide and chloride derivatives of Baylis-Hillman adducts with triarylbismuths as atom-efficient multi-coupling nucleophiles

Bromide and chloride derivatives of Baylis-Hillman adducts have been demonstrated to react efficiently with triarylbismuths affording allylic arylated products in high yields under palladium-catalyzed conditions. Triarylbismuths have been employed in sub-stoichiometric amounts as multi-coupling and atom-efficient nucleophiles in these reactions. The reactivity of both allylic bromides and chlorides was found to be facile and equally efficient in couplings with triarylbismuths.