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[6-(Bis-methylsulfanyl-methylene)-cyclohex-1-enyloxy]-trimethyl-silane is a complex organic compound with the molecular formula C11H24OS2Si. It features a cyclohexene ring with a 6-position oxygen atom connected to a trimethylsilyl group (Si(CH3)3). The cyclohexene ring also has a methylene bridge (-CH2-) between two methylsulfanyl (-SCH3) groups. [6-(Bis-methylsulfanyl-methylene)-cyclohex-1-enyloxy]-trimethyl-silane is primarily used as a reagent in organic synthesis, particularly in the formation of carbon-carbon bonds through the activation of alkenes. Its unique structure allows it to act as a silyl ether protecting group, which can be selectively removed under certain conditions to reveal the original functional group. This property makes it valuable in the synthesis of complex organic molecules where selective protection and deprotection are required.

77149-46-3

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77149-46-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 77149-46-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,1,4 and 9 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 77149-46:
(7*7)+(6*7)+(5*1)+(4*4)+(3*9)+(2*4)+(1*6)=153
153 % 10 = 3
So 77149-46-3 is a valid CAS Registry Number.

77149-46-3Downstream Products

77149-46-3Relevant academic research and scientific papers

PREPARATION OF α-ETHYLENIC KETENE DITHIOACETALS FROM α-OXOKETENE DITHIOACETALS.

Masson, Serge,Thuillier, Andre

, p. 4085 - 4086 (2007/10/02)

1,1-bis(methylthio)-1,3-dienes and 1,1-bis(methylthio)-3-trimethylsilyl-oxy-1,3-dienes were respectively prepared by Wittig olefination and by enol-silylation of α-oxoketene dithioacetals.

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