77201-14-0Relevant academic research and scientific papers
General and selective palladium-catalyzed oxidative esterification of alcohols
Gowrisankar, Saravanan,Neumann, Helfried,Beller, Matthias
, p. 5139 - 5143 (2011)
Selectively esterified: Primary alcohols react with dioxygen as a benign oxidant in a palladium-catalyzed oxidative esterification (see scheme). The corresponding aldehydes and esters are formed highly selectively depending on the catalyst system. The reactions take place in the presence of commercially available ligands without the need for additional organic hydrogen acceptors. Copyright
Palladium-catalyzed aerobic oxidative direct esterification of alcohols
Liu, Chao,Wang, Jing,Meng, Lingkui,Deng, Yi,Li, Yao,Lei, Aiwen
supporting information; experimental part, p. 5144 - 5148 (2011/06/26)
One step from alcohol to ester: A palladium-catalyzed oxidative esterification of various benzylic alcohols with methanol and long-chain aliphatic alcohols was carried out in the presence of molecular oxygen as the oxidant (see scheme). By considering the effects of substitution and potential mechanistic pathways, the applicability of this method to a range of different substrates was shown. Copyright
