77213-17-3Relevant academic research and scientific papers
STEREOSELECTIVE ACYCLIC SYNTHESIS VIA ALLYLMETALS: STRUCTURAL DEPENDENCE IN A LEWIS-ACID CATALYZED ADDITION OF ALLYLTINS TO ALDEHYDES
Koreeda, Masato,Tanaka, Yoshio
, p. 1299 - 1302 (2007/10/02)
Lewis-acid catalyzed reaction of allyltins with aldehydes at -78 deg C provide homoallyl alcohols with high stereoselectivity; 2-alkenyltins in general provide erythro adducts preferentially with an erithro/threo ratio greater than 12/1, whereas only thre
PENTADIENYLSILANES AS NEW REAGENTS OF THE SITESELECTIVE DIENYLMETHYLATION OF ELECTROPHILES PROMOTED BY A LEWIS ACID
Hosomi, Akira,Saito, Masaki,Sakurai, Hideki
, p. 3783 - 3786 (2007/10/02)
(2,4-Pentadienyl)- and (2,4-hexadienyl)trimethylsilanes, prepared from the corresponding pentadienylpotassiums and trimethylchlorosilane, react smoothly with various electrophiles such as acetals, aldehydes and acid halides to give pentadienylation produc
