77215-33-9Relevant academic research and scientific papers
Unsaturated vicinal frustrated phosphane/borane Lewis pairs as ligands in gold(i) chemistry
Ueno, Atsushi,Watanabe, Kohei,Daniliuc, Constantin G.,Kehr, Gerald,Erker, Gerhard
supporting information, p. 4367 - 4370 (2019/04/26)
The P/B FLP 6, formed by the 1,1-hydroboration of dimesitylphosphino(trimethylsilyl)acetylene with HB(C6F5)2 forms the Au(i)X complexes 9a (X: Cl) and 10a (X: NTf2), respectively. Both show marked Au?B interactions. The P/B FLP isomer 8, featuring the bulky SiMe3 substituent at the carbon adjacent to boron forms gold complexes 9b and 10b, both of which show weaker Au?B interactions. Complex 10a was employed in the catalytic hydroamination of a series of alkynes with p-toluidine. Complexes 9 and 10 were characterized by X-ray diffraction.
Ethyl-Zinc(II)-Cation Equivalents: Synthesis and Hydroamination Catalysis
Petersen,Tausch,Schaefer,Scherer,Roesky,Krossing
supporting information, p. 13696 - 13702 (2015/09/22)
Ion-like ethylzinc(II) compounds with weakly coordinating aluminates [Al(ORF)4]- and [(RFO)3Al-F-Al(ORF)3]- (RF=C(CF3)3) were synthesi
SOLVOLYTIC BEHAVIOR OF p-DIMETHYLAMINO-α-BROMOSTYRENE IN WATER SOLUTIONS
Schubert, W.M.,Green, David C.
, p. 4237 - 4240 (2007/10/02)
Nmr and UV studies show that p-dimethylamino-α-bromostyrene, I, undergoes SN1 reaction in H2O and HClO4 (kSN1=6x1E-1sec-1 at 25 deg C).The vinyl cation has an extraordinary selectivity for capture by aromatic amines relative to H2O, including I itself to give the dimer II.
