77301-90-7Relevant articles and documents
New thiosubstituted butadiene and butenyne compounds from hexachloro-butenes and thiols
Ibis, Cemil,Bal, Tuelay
, p. 431 - 438 (2003)
2,3-Di-H-butene compound 1 gave compounds 3a-f, 4a, 4e, and 5a-d in the presence of thiols 2a-f and Et3N (or NaOH). Compound 7e was obtained from the reaction of 1,3-Di-H-butene 6 with naphthylthiol in DMF. In the presence of NaOH, compound 6 a
Reactions of Polychloro-1,3-butadienes and Polychlorobutenes with Thiolates
Roedig, Alfred,Ibis, Cemil,Zaby, Gottfried
, p. 684 - 698 (2007/10/02)
On treatment of perchlorobutadiene (1), of the pentachlorobutadienes 10 and 18, or of the hexachlorobutenes 21, 25, and 32 with thiolates in DMSO a very fast and extensive replacement of chlorine is observed even at room temperature.The reactions 1 -> 7,