77302-56-8

Upstream product

• 87-69-4 L-Tartaric acid 
• 2216-51-5 (-)-menthol 
• 147-73-9 meso-tartaric acid 
• 15356-70-4 menthol 
• 87-69-4 tartaric acid 
• 87-91-2 diethyl (2R,3R)-tartrate 

Downstream Products

• 1318254-27-1 C₃₅H₅₅O₇P 
• 1318254-26-0 C₂₉H₄₉O₇P 
• 1318254-25-9 C₂₈H₄₇O₇P 
• 1318254-24-8 C₃₇H₅₃O₇P 
• 1318254-19-1 C₃₃H₅₁O₈P 
• 1318254-17-9 C₃₃H₅₁O₇P 
• 1318254-34-0 C₃₂H₅₁O₈P 
• 1318254-33-9 C₃₃H₅₁O₇P 
• 1318254-14-6 C₃₄H₅₇O₇P 
• 1318254-11-3 C₃₂H₅₇O₇P 
• 1318253-98-3 C₂₆H₄₂Cl₃O₇P 
• 1026024-01-0 (4R,5R)-bis[(1R,2S,5R)-menth-1-yloxycarbonyl]-2-[(R)-1-phenyleth-1-yloxy]-1,3,2-dioxaphospholane 
• 1026023-96-0 (4R,5R)-bis((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl) 2-chloro-1,3,2-dioxaphospholane-4,5-dicarboxylate 

Relevant academic research and scientific papers

PHASE CHANGE INK COMPONENTS AND METHODS OF MAKING THE SAME

A solid ink composition comprising an amorphous component, a crystalline material, and optionally, a colorant, which are suitable for ink jet printing, including printing on coated paper substrates, and methods for making the same. In embodiments, the crystalline and amorphous components are synthesized from an esterification reaction of tartaric acid with an alcohol.

2-Chloro-(4R,5R)-bis[(1R,2S,5R)-menth-1-yloxycarbonyl]-1,3, 2-dioxaphospholane: A practical chiral pool-derived reagent for determining enantiomeric purity of alcohols

(Chemical Equation Presented) 2-Chloro-(4R,5R)-bis[(1R,2S,5R)-menth-1- yloxycarbonyl)]-1,3,2-dioxaphospholane is a practical reagent for reliably determining enantiomeric purity of chiral alcohols via 31P NMR spectroscopy. The compound is available as a crystalline solid on a 20 g scale from PCl3 and bis[(1R,2S,5R)-menth-1-yl] tartrate. It is comparatively inert toward spontaneous hydrolysis under conventional laboratory conditions but undergoes quantitative substitution of alkoxide for chloride if treated with a chiral alcohol. Nonequivalent 31P NMR signals of diastereomeric 2-alkoxy-1,3,2-dioxophospholanes were dispersed by ～1.4-0.1 ppm. The associated integral ratios reflected enantiomeric purities of preweighted samples of (R)- and (S)-1-phenylethanol, (+)- and (-)-menthol, and a set of primary, secondary, and tertiary alcohols with a precision of ±0.4-1.0%.