77329-37-4Relevant academic research and scientific papers
NEIGHBOURING GROUP PARTICIPATION IN REACTIONS BETWEEN IODINE AND Ph3Sn(CH2)nS(O)mC6H4Me-p
Wardell, James L.,Wigzell, John McM.
, p. C24 - C26 (1981)
Reactions of Ph3Sn(CH2)nS(O)mC6H4Me-p (n = 2, 3 or 4; m = 0, 1 or 2) with iodine in CCl4 result in phenyl-tin bond cleavage.The relative reactivities indicate intramolecular nucleophilic catalysis by the sulphur-containing substituents.
Sulphur-substituted Organotin Compounds. Part 8. Preparation and Reactions of 3-(p-Tolylthio)propyl- and 4-(p-Tolylthio)butyl-triphenyltin. Interactions with Tetracyanoethylene
Wardell, James L.,Wigzell, John McM.
, p. 2321 - 2326 (2007/10/02)
The reactions of SnPh3 (n= 3 or 4) with mercury(II) chloride, bromine and iodine lead to phenyl-tin bond cleavage.In contrast, reactions with methyl iodide provide SnPh3 and MeSC6H4Me-p.Charge-transfer adducts are formed between SnPh3 (n= 1-4) and tetracyanoethylene or p-bromoanil.The values of λmax. of the complexes indicate similar donor character for SnPh3 (n= 2,3, or 4); however, the compound SnPh3(CH2SC6H4Me-p) is a stronger donor.
