77341-47-0

Upstream product

• 21462-06-6 2-endo,3-endo-bicyclo[2.2.1]heptane-2,3-diol 
• 100-52-7 benzaldehyde 

Downstream Products

• 77085-41-7 benzoyloxy-2 endo hydroxy-3 endo bicyclo <2.2.1> heptane 
• 77085-37-1 bromo-2 exo hydroxy-3 endo bicyclo<2.2.1>heptane 
• 77085-42-8 1-((1R,2R,6S,7S)-4-Phenyl-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-4-yl)-pyrrolidine-2,5-dione 

Relevant academic research and scientific papers

ACTION DU N-BROMOSUCCINIMIDE SUR LES DIOXOLANNES EN SERIE BICYCLOHEPTANIQUE. LIMITATION DES TRANSPOSITIONS DE WAGNER-MEERWEIN

Vicinal benzoyloxy-trans-bicycloheptanic bromhydrins, otherwise difficult to obtain are formed from N-bromosuccinimide and norbornanes bearing a 2-aryl-1,3 dioxolane skeleton.The greater stability of the intermediate dioxolenium ion reduces the tendency towards both Wagner-Meerwein rearrangement and neighbouring group participation by chlorine, processes usually observed when a less stable intermediate is involved.Nevertheless, methoxycarbonyl neighbouring group participation and Wagner-Meerwein rearrangement occur in methoxycarbonylbicycloheptane and in a bornanic compound respectively.