77411-98-4

Basic information

• Product Name: 3,7-dimethyl-2-(phenylthio)-1-(trimethylsilyl)oct-6-en-3-ol
• CAS NO: 77411-98-4
• Molecular Weight: 336.614
• Mol File: 77411-98-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3,7-dimethyl-2-(phenylthio)-1-(trimethylsilyl)oct-6-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-dimethyl-2-(phenylthio)-1-(trimethylsilyl)oct-6-en-3-ol(77411-98-4)
• EPA Substance Registry System: 3,7-dimethyl-2-(phenylthio)-1-(trimethylsilyl)oct-6-en-3-ol(77411-98-4)

Safety Data

• Hazardous Substances Data: 77411-98-4(Hazardous Substances Data)

Upstream product

• 5042-53-5 1-(phenylsulfanyl)acetone 
• 61829-51-4 2-(phenylthio)-3-(trimethysilyl)propanenitrile 
• 61829-54-7 2-(phenylthio)-1-(trimethylsilyl)butan-3-one 
• 693-25-4 n-pentylmagnesium bromide 

Downstream Products

• 31236-12-1 3,7-Dimethyl-octa-2,6-dienyl-phenylsulfoxid 
• 31162-76-2 3,7-dimethyl-1-(phenylthio)octa-2,6-diene 
• 77412-14-7 (5-Isopropenyl-2-methyl-2-phenylsulfanyl-cyclopentylmethyl)-trimethyl-silane 
• 77411-99-5 3,7-dimethyl-3-phenylthio-octa-1,6-diene 

Relevant articles and documents

The Formation of Allyl Sulphides by Phenylthio-migration: Control by Silicon

When γ-silyl-β-phenylthio-alcohols are treated with acid, the strategically placed silyl group encourages the rearrangement of the phenylthio-group, both from a secondary migration origin to a secondary migration terminus, and from a secondary migration origin to a tertiary migration terminus (4)->(6).Geraniol/nerol (12) and linalool (14) have been synthesised from a common intermediate (11) using this type of reaction.Phenylthio-migration from a tertiary migration origin (17)->(3) can be controlled to a limited extent by a suitably placed silyl group, but it is easier to achieve direct β-elimination of the silyl and phenylthio-groups (17)->(18).