774599-35-8

Upstream product

• 1152-39-2 p-methylphenyl-1-thio-β-D-galactopyranoside 
• 2746-25-0 p-Methoxybenzyl bromide 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 774599-36-9 (2R,3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-1,3,4,5-tetrakis-(4-methoxy-benzyloxy)-hexan-2-ol 
• 774599-37-0 tert-Butyl-dimethyl-[(2S,3S,4S)-2,3,4-tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-enyloxy]-silane 
• 774599-24-5 (3R,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-1,3,4,5-tetrakis-(4-methoxy-benzyloxy)-hexan-2-one 
• 774599-25-6 (2S,3S,4S)-2,3,4-Tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-en-1-ol 
• 774599-23-4 (2S,3R,4S,5R)-2,3,4,6-Tetrakis-(4-methoxy-benzyloxy)-hexane-1,5-diol 
• 774599-38-1 (2R,3S,4S)-2,3,4-Tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-enal 
• 864738-48-7 2,3,4,6-tetra-O-4-methoxybenzyl-D-galactopyranose 

Relevant academic research and scientific papers

A mild and efficient method for the selective cleavage of primary p-methoxybenzyl protecting group of saccharides by Co2(CO)8-Me2PhSiH-CO system

A mild and efficient method to selectively cleave p-methoxybenzyl (PMB) ether with a catalytic amount of Co2(CO)8, hydrosilane and CO (1 atm) is presented. The cleavage reaction shows regioselectivity to primary O-PMB of a variety of

Synthesis of an isostere of an O-linked glycopeptide

(Chemical Equation Presented) A route for the synthesis of an electrophilic, carbocyclic galactose equivalent from D-galactose is described. The strategy utilizes ring-closing metathesis with Grubbs's second-generation catalyst as the key step. The galact