864738-48-7

Upstream product

• 25878-60-8 D-galactose pentaacetate 
• 13992-16-0 phenyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-galactopyranoside 
• 105-13-5 4-Methoxybenzyl alcohol 
• 10257-28-0 D-Galactose 
• 2746-25-0 p-Methoxybenzyl bromide 
• 1152-39-2 p-methylphenyl-1-thio-β-D-galactopyranoside 
• 774599-35-8 4-methylphenyl 2,3,4,6-tetra-O-[(4-methoxybenzyl)]-1-thio-β-D-galactopyranoside 

Downstream Products

• 774599-23-4 (2S,3R,4S,5R)-2,3,4,6-Tetrakis-(4-methoxy-benzyloxy)-hexane-1,5-diol 
• 34324-89-5 (2S,3R,4E)-1-(β-D-galactopyranosyloxy)-2-(hexadecanoylamino)-3-hydroxyoctadec-4-ene 
• 774599-36-9 (2R,3S,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-1,3,4,5-tetrakis-(4-methoxy-benzyloxy)-hexan-2-ol 
• 774599-37-0 tert-Butyl-dimethyl-[(2S,3S,4S)-2,3,4-tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-enyloxy]-silane 
• 774599-24-5 (3R,4R,5S)-6-(tert-Butyl-dimethyl-silanyloxy)-1,3,4,5-tetrakis-(4-methoxy-benzyloxy)-hexan-2-one 
• 774599-25-6 (2S,3S,4S)-2,3,4-Tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-en-1-ol 
• 774599-38-1 (2R,3S,4S)-2,3,4-Tris-(4-methoxy-benzyloxy)-5-(4-methoxy-benzyloxymethyl)-hex-5-enal 

Relevant academic research and scientific papers

Electrochemical Synthesis of Glycosyl Fluorides Using Sulfur(VI) Hexafluoride as the Fluorinating Agent

This manuscript describes the electrochemical synthesis of 17 different glycosyl fluorides in 73-98% yields on up to a 5 g scale that relies on the use of SF6 as an inexpensive and safe fluorinating agent. Cyclic voltammetry and related mechanistic studies carried out subsequently suggest that the active fluorinating species generated through the cathodic reduction of SF6 are transient under these reductive conditions and that the sulfur and fluoride byproducts are effectively scavenged by Zn(II) to generate benign salts.

Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.

Synthesis and assessment of globotriose-chitosan conjugate, a novel inhibitor of Shiga toxins produced by Escherichia coli

Shiga toxin (Stx)-producing Escherichia coli (STEC) causes diarrhea and colitis in humans that can develop into a life-threatening hemolytic uremic syndrome (HUS). Developing efficient means of controlling STEC diseases, for which no drugs or vaccines are

Synthesis of an isostere of an O-linked glycopeptide

(Chemical Equation Presented) A route for the synthesis of an electrophilic, carbocyclic galactose equivalent from D-galactose is described. The strategy utilizes ring-closing metathesis with Grubbs's second-generation catalyst as the key step. The galact