77472-76-5

Upstream product

• 1774-66-9 3-(4-bromophenyl)-1-phenylprop-2-en-1-one 
• 101855-03-2 3-(4-bromo-phenyl)-3-methoxyamino-1-phenyl-propan-1-one 
• 124-41-4 sodium methylate 
• 22966-09-2 (2E)-3-(4-bromophenyl)-1-phenylprop-2-en-1-one 

Downstream Products

• 109831-06-3 (2R,3S)-2-Benzoyl-3-(4-bromo-phenyl)-aziridine-1-carboxylic acid phenylamide 

Relevant academic research and scientific papers

Efficient aziridination of α,β-unsaturated ketones with O-(2,4-dinitrophenyl)-hydroxylamine

The aziridination of α,β-unsaturated ketones with O-(2,4-dinitrophenyl)-hydroxylamine and tertiary amine was developed. trans-Aziridines were obtained exclusively in good yields. The reaction is proposed to occur via an aminimide intermediate. Copyright T

Direct NH-aziridination of α,β-unsaturated ketones

1-Aryl-α,β-unsaturated ketones were directly aziridinated, N-unsubstituted, in a one-pot reaction with satisfactory yields by N,N′-diamino-1,4-diazoniabicyclo[2.2.2]octane dinitrate, a nitrogen-nitrogen ylide precursor, in the presence of sodium hydride.