77480-52-5Relevant academic research and scientific papers
FIRST SYNTHESIS OF AN EPIMER OF (+/-)-PENTENOMYCIN I
Shono, Tatsuya,Matsumura, Yoshihiro,Yamane, Shin-ichiro,Suzuki, Masahito
, p. 1619 - 1620 (1980)
An epimer of pentenomycin I was first synthesized starting from a furan derivative.The synthetic route involves acid-catalyzed transformation of a 2,5-dihydro-2,5-dimethoxyfuran derivative to a cyclopentenone derivative, which is a key intermediate in the synthesis of the expected compound.
Synthesis of (±) epipentenomycin I and III
Phutdhawong, Weerachai,Pyne, Stephen G.,Baramee, Apiwat,Buddhasukh, Duang,Skelton, Brian W.,White, Allan H.
, p. 6047 - 6049 (2007/10/03)
A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy- and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide.
Intramolecular acylation of α-sulfinyl carbanion: A facile synthesis of (±)-pentenomycin I and (±)-epipentenomycin I
Pohmakotr,Popuang
, p. 275 - 278 (2007/10/02)
(±)-Pentenomycin I and (±)-epipentenomycin I were synthesized, starting from methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate. The key reaction involved the intramolecular acylation of α-sulfinyl carbanion and pyrolysis of the resulting product.
