77480-52-5Relevant articles and documents
FIRST SYNTHESIS OF AN EPIMER OF (+/-)-PENTENOMYCIN I
Shono, Tatsuya,Matsumura, Yoshihiro,Yamane, Shin-ichiro,Suzuki, Masahito
, p. 1619 - 1620 (1980)
An epimer of pentenomycin I was first synthesized starting from a furan derivative.The synthetic route involves acid-catalyzed transformation of a 2,5-dihydro-2,5-dimethoxyfuran derivative to a cyclopentenone derivative, which is a key intermediate in the synthesis of the expected compound.
Intramolecular acylation of α-sulfinyl carbanion: A facile synthesis of (±)-pentenomycin I and (±)-epipentenomycin I
Pohmakotr,Popuang
, p. 275 - 278 (2007/10/02)
(±)-Pentenomycin I and (±)-epipentenomycin I were synthesized, starting from methyl 2,2-dimethyl-1,3-dioxolane-4-carboxylate. The key reaction involved the intramolecular acylation of α-sulfinyl carbanion and pyrolysis of the resulting product.
A stereospecific total synthesis of (±)-epipentenomycin I, (±)-epipentenomycin II and (±)-epipentenomycin III
Smith III,Pilla
, p. 4691 - 4694 (2007/10/02)
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