7749-82-8Relevant academic research and scientific papers
Thermolyse, pyrolyse et photolyse d'heterocycles germanies et soufres a 4 et 5 chainons: especes intermediaires a germanium doublement lie
Barrau, J.,Rima, G.,El-Amine, M.,Satge, J.
, p. 39 - 50 (1988)
The thermolysis, pyrolysis and photolysis of thiagermetane , dithiagermolane and thiagermetane dioxide have been studied.Thiagermetane and dithiagermolane decompose leading to various new germylated heterocycles: , and probably proceed by two competitive mechanisms which involve the transient species germaethene , germathione , thiagermirane and thiadigermetane .Pyrolysis of thiagermetane dioxide also involves germaethene and probably a new doubly-bonded germanium species, the germasulfene (by mass spectroscopy), which finally gives germoxanes (Me2GeO)n (n = 3,4).
