77495-32-0Relevant academic research and scientific papers
BIOMIMETIC POLYENE CYCLIZATIONS - ASYMMETRIC INDUCTION IN THE CYCLIZATION OF A CHIRAL DIENIC IMINE
Demailly, Gilles,Solladie, Guy
, p. 3355 - 3358 (2007/10/02)
The acid-catalyzed cyclization of the chiral aldimine prepared from trans-5,9 dimethyldeca-5,9-dienal and (-)S-α-phenyl-ethylamine affords diastereoisomeric amino-5 dimethyl-2,9 octalines, the asymmetric induction being 65 percent in the trans-trans series and 35 percent in the cis-trans series.
