77515-69-6Relevant academic research and scientific papers
STUDIES ON HISTRIONICOTOXIN: REARRANGEMENT OF THE SPIROCYCLIC HISTRIONICOTOXIN CARBON SKELETON INTO THE FUSED PUMILIOTOXIN SKELETON
Venit, John J.,Magnus, Philip
, p. 4815 - 4818 (1980)
On the treatment with acid the spirocyclic ketoamine 5 undergoes a retro-Mannich reaction followed by recondensation to give the unsaturated imine 8, thus converting the histrionicotoxin carbon skeleton into the pumiliotoxin C skeleton.
