STUDIES ON HISTRIONICOTOXIN: REARRANGEMENT OF THE SPIROCYCLIC HISTRIONICOTOXIN CARBON SKELETON INTO THE FUSED PUMILIOTOXIN SKELETON

DOI: 10.1016/0040-4039(80)80147-X

Source and publish data:

Tetrahedron Letters p. 4815 - 4818 (1980)

Update date:2022-08-03

Topics:

Authors:

Venit, John J.

Magnus, Philip

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Article abstract of DOI:10.1016/0040-4039(80)80147-X

On the treatment with acid the spirocyclic ketoamine 5 undergoes a retro-Mannich reaction followed by recondensation to give the unsaturated imine 8, thus converting the histrionicotoxin carbon skeleton into the pumiliotoxin C skeleton.

Full text of DOI:10.1016/0040-4039(80)80147-X

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