Tetrahedron Letters p. 4815 - 4818 (1980)
Update date:2022-08-03
Topics:
Venit, John J.
Magnus, Philip
On the treatment with acid the spirocyclic ketoamine 5 undergoes a retro-Mannich reaction followed by recondensation to give the unsaturated imine 8, thus converting the histrionicotoxin carbon skeleton into the pumiliotoxin C skeleton.
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Doi:10.1021/ja01874a076
(1939)Doi:10.1021/jm00313a013
(1967)Doi:10.1055/s-0033-1338643
(2014)Doi:10.1021/ja00193a034
(1989)Doi:10.1021/jm00139a013
(1981)Doi:10.1021/ja00399a052
(1981)
