77547-99-0Relevant academic research and scientific papers
SOME HIGHLY STERICALLY HINDERED ORGANO-SILANOLS AND -SILOXANES
Eaborn, Colin,Safa, Kazem D.
, p. 7 - 14 (1982)
Reaction of the iodides TsiSiMe2I and TsiSiPh2I, (Tsi=(Me3Si)3C) with AgClO4 in t-BuOH provides a route to the silanols TsiSiMe2OH and (Me3Si)2C(SiPh2Me)(SiMe2OH), respectively.TsiSiMe2OH gives the disiloxane TsiSiMe2OSiMe3 when treated with either (a) Me
AN UNUSUAL BICYCLIC TETRASILOXANE
Eaborn, Colin,Hitchcock, Peter B.,Safa, Kazem D.
, p. 187 - 194 (1981)
The compound (Me3Si)3CSiPh2I react with AgClO4 in CH3CN ("dried", but evidently containing some water) to give the tetrasiloxane 1,3,3',5,7,7'-hexamethyl-4,4',8,8'-tetra(trimethylsilyl)-2,6,9-trioxa-1,3,5,7-tetrasilabicyclononane, the structure of
The Methanolysis of the Highly Sterically Hindered Organosilicon Compounds (Me3Si)3CSiMe2X with X=OSO2CF3, OCN or OClO3. A Mechanistic Enigma
El-Kaddar, Yousef Y.,Eaborn, Colin,Lickiss, Paul D.,Reed, David E.
, p. 1753 - 1759 (2007/10/02)
Rates of solvolysis have been determined for the compounds (Me3Si)3CSiMe2X with X=OSO2CF3, 3, or OCN, 6, (Me3Si)3CSiMe(OMe)OSO2CF3, 5, and (Me3Si)2C(SiMePh2)(SiMe2OSO2CF3), 4, in MeOH alone or containing water or NaOMe.The methanolyses of the trifluoromet
Oxidatively Assisted Nucleophilic Substitution of Organosilicon Iodides
Al-Wassil, Abdulaziz I.,Eaborn, Colin,Saxena, Anil K.
, p. 974 - 975 (2007/10/02)
The iodides (Me3Si)3CSiMe2I, (Me3Si)3CSiPh2I, and But3SiI react with m-chloroperbenzoic acid to give the hydroxides (Me3Si)3CSiMe2OH, (Me3Si)2C(SiPh2Me)(SiMe2OH), and But3SiOH, respectively, in MeOH alone, and the corresponding chlor
STERICALLY-HINDERED ORGANOSILICON PERCHLORATES
Dua, Sujan S.,Eaborn, Colin
, p. 21 - 26 (2007/10/02)
The prechlorates (Me3Si)3C(SiMe2OClO3) and (Me3Si)2C(SiPh2Me)(SiMe2ClO3) have been obtained by treatment of the iodides (Me3Si)3C(SiMe2I) and (Me3Si)3C(SiPh2I), respectively, with AgClO4 in CH2Cl2.The perchlorates react with MeOH to give the methoxides (M
