SOME HIGHLY STERICALLY HINDERED ORGANO-SILANOLS AND -SILOXANES

DOI: 10.1016/S0022-328X(00)85698-3

Source and publish data:

Journal of Organometallic Chemistry p. 7 - 14 (1982)

Update date:2022-08-11

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Authors:

Eaborn, Colin

Safa, Kazem D.

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Article abstract of DOI:10.1016/S0022-328X(00)85698-3

Reaction of the iodides TsiSiMe2I and TsiSiPh2I, (Tsi=(Me3Si)3C) with AgClO4 in t-BuOH provides a route to the silanols TsiSiMe2OH and (Me3Si)2C(SiPh2Me)(SiMe2OH), respectively.TsiSiMe2OH gives the disiloxane TsiSiMe2OSiMe3 when treated with either (a) Me

Full text of DOI:10.1016/S0022-328X(00)85698-3

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