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Usage

Uses

Used in Silicone Polymer Production:
1,3-Dichlorotetraphenyldisiloxane serves as a crucial precursor in the manufacturing process of silicone polymers, which are known for their wide range of applications across various industries due to their unique properties such as heat resistance, flexibility, and biocompatibility.
Used in Organic Synthesis:
As a reagent in organic synthesis, 1,3-Dichlorotetraphenyldisiloxane is utilized for its ability to facilitate specific chemical reactions, contributing to the creation of a diverse array of organic compounds for different applications.
Used in Material Development:
1,3-Dichlorotetraphenyldisiloxane is employed in the development of materials with enhanced robustness, leveraging its high thermal stability and resistance to oxidative degradation. This makes it suitable for applications where materials are exposed to harsh conditions, such as high temperatures or oxidative environments.
Used in Specialty Chemicals Industry:
In the specialty chemicals industry, 1,3-Dichlorotetraphenyldisiloxane is used as a building block for the synthesis of complex organosilicon compounds that may have unique properties or specific uses in various high-tech applications.

InChI:InChI=1/C24H20Cl2OSi2/c25-28(21-13-5-1-6-14-21,22-15-7-2-8-16-22)27-29(26,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H

Upstream product

• 80-10-4 diphenylsilyl dichloride 
• 15545-80-9 1,1,3,3-tetraphenyldisiloxane 

Downstream Products

• 1104-93-4 1,1,3,3-tetraphenyldisiloxane-1,3-diol 
• 58110-09-1 1.3-Di-tert.-butylperoxytetraphenyldisiloxan 
• 1092815-51-4 [5]-trovacenyldiphenylsiloxy-diphenylsilanol 
• 1276694-52-0 syn-1,3,9,11-tetramethyl-5,5,7,7,13,13,15,15-octaphenyltricyclo[9.5.1.1(3,9)]octasiloxane 
• 18842-38-1 1,1,3,3-tetraphenyl-1,3-di(prop-2-enyl)disiloxane 
• 136745-52-3 pentaphenylboracyclotrisiloxane 
• 141613-72-1 (C₆H₅BO)((C₆H₅)2SiO)3 
• 74711-14-1 2,2-bis(aminodimethylsiloxy)tetraphenylcyclotrisiloxane 
• 74692-05-0 2,2-bis(chlorodimethylsiloxy)tetraphenylcyclotrisiloxane 
• 18891-02-6 2,2-dihydroxy-4,4,6,6-tetraphenylcyclotrisiloxane 
• 21450-42-0 2,2-dimethoxytetraphenylcyclotrisiloxane 
• 75-77-4 chloro-trimethyl-silane 
• 16069-25-3 2,2-dichloro-4,4,6,6-tetraphenylcyclotrisiloxane 
• 58194-85-7 1,3-dichloro-1,3-diphenyl-1,3-dihydro-benzo[1,2,5]oxadisilole 

Relevant academic research and scientific papers

Synthesis and characterization of unsymmetrical double-decker siloxane (Basket Cage)

The one-pot synthesis of an unsymmetrical double-decker siloxane with a novel structure via the reaction of double-decker tetrasodiumsilanolate with 1 equiv. of dichlorotetraphenyldisiloxane in the presence of an acid is reported herein for the first time. The target compound bearing all phenyl substituents on the unsymmetrical siloxane structure was successfully obtained, as confirmed by 1H-NMR, 13C-NMR, 29Si-NMR, IR, MALDI-TOF, and X-ray crystallography analyses. Additionally, the thermal properties of the product were evaluated by TG/DTA and compared with those of other siloxane cage compounds.

Building blocks for oligomeric siloxanes –selective chlorination of hydrido-siloxanes

A new method was developed to achieve highly selective monochlorination of α,ω-dihydridosiloxanes, ((H)Me2SiO-(SiMe2O)n-SiMe2(H), n = 0–2; (H)R2Si–O-SiR2(H); R = Me, iPr, Ph; 3,5-dihydridooctamethyltetrasiloxane, Me3SiO-(Si(H)MeO)2–SiMe3) with trichloroisocyanuric acid (TCCA). The dependence of the selectivity of the monochlorination on the siloxane chain length is also discussed.

Stereochemistry of the reaction of cis,trans,cis-2,4,6,8-tetraisocyanato-2, 4,6,8-tetramethylcyclotetrasiloxane with triphenylsilanol and 1,1,3,3-tetraphenyldisiloxane-1,3-diol

All-cis-2,4,6,8-tetramethyl-2,4,6,8-tetrakis(triphenylsiloxy) cyclotetrasiloxane (4) and syn-1,3,9,11-tetramethyl-5,5,7,7,13,13,15,15- octaphenyltricyclo[9.5.1.13,9]octasiloxane (5) were synthesized by the reaction of cis,trans,cis-[MeSi(NCO)O]4 (1) with Ph 3SiOH (2) and [Ph2Si(OH)]2O (3), respectively, in the presence of pyridine for the sake of investigating the synthesis of ladder polysilsesquioxanes with perfect siloxane frameworks. Their stereostructures were confirmed by nuclear magnetic resonance spectra and X-ray crystallography, which revealed that 4 and 5 did not retain the stereostructure of the precursor 1. This result was caused by the racemization of 1 with pyridine, and a subsequent nucleophilic substitution reaction of 1 with 2 or 3, including inversion and retention of the configuration at the silicon atoms.

Synthesis and structure of syn,anti,syn-pentacyclic ladder oligomethylsilsesquioxane

Novel pentacyclic ladder oligomethylsilsesquioxane was synthesized using cis,trans,cis-[MeSi(NCO)O]4 as a building block. This compound was isolated in 13% yield by reprecipitation from the reaction mixture. X-ray crystallography revealed that pentacyclic rings assume a syn,anti,syn- configuration, resulting in the tube-like structure.