776313-50-9Relevant academic research and scientific papers
Electrophilic difluoro(phenylthio)methylation: Generation, stability, and reactivity of α-fluorocarbocations
Betterley, Nolan M.,Surawatanawong, Panida,Prabpai, Samran,Kongsaeree, Palangpon,Kuhakarn, Chutima,Pohmakotr, Manat,Reutrakul, Vichai
, p. 5666 - 5669 (2013/12/04)
Electrophilic difluoro(phenylthio)methylation of allylsilanes has been achieved using bromodifluoro(phenylthio)methane (PhSCF2Br) and silver hexafluoroantimonate (AgSbF6). The structural assignment and observation of α-fluorocarbocation were substantiated by NMR and theoretical calculations. Detailed mechanistic and electronic studies have provided a fundamental understanding of the reactivity and stability of the difluoro(phenylthio)methylium cation (PhSCF2+).
Difluorophenylsulfanylmethyl radical and difluoromethylene diradical synthons: gem-difluoromethylene building block
Reutrakul, Vichai,Thongpaisanwong, Thanchanok,Tuchinda, Patoomratana,Kuhakarn, Chutima,Pohmakotr, Manat
, p. 6913 - 6915 (2007/10/03)
Bromodifluorophenylsulfanylmethane has been demonstrated to be a highly versatile gem-difluoromethylene (CF2) building block via the reaction of difluorophenylsulfanylmethyl radical with olefins. gem-Difluoroalkenes and products containing a mi
