19093-37-9

Basic information

• Product Name: ALLYL PHENYL SULFOXIDE
• Synonyms: ALLYL PHENYL SULFOXIDE;(allylsulphinyl)benzene;ALLYL PHENYL SULFOXIDE, TECH.;(2-Propenylsulfinyl)benzene;(Allylsulfinyl)benzene;Phenyl (2-propenyl) sulfoxide;Phenyl allyl sulfoxide;Einecs 242-811-4
• CAS NO: 19093-37-9
• Molecular Formula: C₉H₁₀OS
• Molecular Weight: 166.24
• EINECS: 242-811-4
• Product Categories: monomer
• Mol File: 19093-37-9.mol
• Article Data: 158

Chemical Properties

• Boiling Point: 85 °C0.3 mm Hg(lit.)
• Flash Point: 133.2°C
• Appearance: /
• Density: 1.122 g/mL at 20 °C(lit.)
• Vapor Pressure: 0.0025mmHg at 25°C
• Refractive Index: n20/D 1.578
• CAS DataBase Reference: ALLYL PHENYL SULFOXIDE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYL PHENYL SULFOXIDE(19093-37-9)
• EPA Substance Registry System: ALLYL PHENYL SULFOXIDE(19093-37-9)

Safety Data

• Hazard Codes: Xn
• Statements: 20/21
• Safety Statements: 23-36/37
• WGK Germany: 3
• Hazardous Substances Data: 19093-37-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 815, 1983 DOI: 10.1055/s-1983-30526Tetrahedron Letters, 35, p. 1413, 1994 DOI: 10.1016/S0040-4039(00)76232-0

InChI:InChI=1/C9H10OS/c1-2-8-11(10)9-6-4-3-5-7-9/h2-7H,1,8H2

Upstream product

• 67652-99-7 (+/-)_S-(E)-1-(phenylsulfinyl)prop-1-ene 
• 107-18-6 allyl alcohol 
• 931-59-9 benzenesulfenyl chloride 
• 13865-11-7 phenyl propargyl sulfoxide 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 
• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 106-95-6 allyl bromide 
• 1208-20-4 S-phenyl benzenethiosulfinate 
• 2622-05-1 allylmagnesium bromide 
• 4972-29-6 benzenesulphinyl chloride 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 5296-64-0 allyl phenyl thioether 
• 137956-96-8 Prop-2-ene-1-sulfinic acid (R)-((1S,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide 

Downstream Products

• 113107-69-0 methyl E-2,2-dimethyl-5-(phenylthio)-4-pentenoate 
• 113107-68-9 methyl 2,2-dimethyl-3-(phenylthio)-4-pentenoate 
• 52072-12-5 α-acetoxyallyl phenyl sulfide 
• 5296-64-0 allyl phenyl thioether 
• 882-33-7 diphenyldisulfane 
• 125417-53-0 Diethyl-((E)-3-phenylsulfanyl-allyl)-amine 
• 169137-89-7 S-(prop-2-enyl)-S-phenyl-N-(p-tolylsulfonyl) sulfoximide 
• 54234-79-6 propyl phenyl sulfoxide 
• 124306-11-2 (Z)-trimethyl((1-phenylbuta-1,3-dien-1-yl)oxy)silane 
• 124306-47-4 trimethyl[(1-phenylbuta-1,3-dien-1-yl)oxy]silane 
• 1315281-53-8 C₁₄H₂₀OSi 
• 54234-79-6 (R)-(propylsulfinyl)benzene 
• 109120-75-4 phenyl n-propyl sulfoxide 
• 72024-41-0 S-phenyl benzylcarbamothioate 

Relevant articles and documents

Chemoselective Method for the Preparation of Phenyl Sulfoxides by the Oxidation of Phenyl Sulfides with 2-Hydroperoxy-2-methoxypropane

Phenyl sulfoxides are easily prepared by the chemoselective oxidation of the corresponding sulfides with molecular equivalents of 2-hydroperoxy-2-methoxypropane.This reagent is generated from 2,3-dimethyl-2-butene by ozonization in methanol.

Selective oxidation of sulfides to sulfoxides using IBX-esters

IBX-esters (esters of 2-iodoxybenzoic acid) are convenient hypervalent iodine reagents for the clean and selective oxidation of organic sulfides to sulfoxides. This reaction proceeds without over-oxidation to sulfones and is compatible with the presence of the hydroxy group, double bond, phenol ether, benzylic carbon, and various substituted phenyl rings in the molecule of the substrate.

COMPOSITES, METHODS AND USES THEREOF

The present invention relates, in general terms, to methods of catalysing a reaction, including the steps of contacting a chemical entity comprising a sulphide moiety with a composite and an oxidant. The composite acts as a heterogeneous catalyst to oxidise the sulphide moiety. The present invention also relates to composites, methods of synthesising the composites and its use as a catalyst thereof.

Polyoxometalate-Based Organic-Inorganic Hybrids as Heterogeneous Catalysts for Cycloaddition of CO2with Epoxides and Oxidative Desulfurization Reactions

Self-assembly of polyoxometalates, transition metal salts, and 2,6-bis(2′-pyridyl)-4-hydroxypyridine (LOH) obtained four organic-inorganic hybrids [Co2.5(LOH)(LO)2(H2O)2(PW12O39)]·3CH3CN·2OH (1), [Zn1.5(LOH)3]·(PMo12O40)·CH3OH·2H2O (2), [Cd1.5(LOH)3]·(PW12O40)·2CH3OH·1.5H2O (3), and [Mn(LOH)2]·(PW12O40)·2CH3CN·H3O (4). Hybrid 1 exhibits an extended chain, which could be further connected into a 3D supramolecular architecture by H-bonds. Hybrids 2-4 feature monomolecular structures, which are further bridged via H-bonds to yield charming 3D supramolecular structures. Noteworthy, 1 and 2 can be employed as recyclable and highly efficient heterogeneous catalysts. The activated 1 displays a high catalytic activity for the cycloaddition reaction of CO2 and epoxides. Hybrid 2 exhibits an excellent catalytic performance for the oxidative desulfurization reaction.