77657-90-0

Basic information

• Product Name: Butanal, 4-(phenylthio)-
• CAS NO: 77657-90-0
• Molecular Formula: C10H12OS
• Molecular Weight: 180.271
• Mol File: 77657-90-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Butanal, 4-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanal, 4-(phenylthio)-(77657-90-0)
• EPA Substance Registry System: Butanal, 4-(phenylthio)-(77657-90-0)

Safety Data

• Hazardous Substances Data: 77657-90-0(Hazardous Substances Data)

Upstream product

• 5851-37-6 4-(phenylthio)butan-1-ol 
• 35756-39-9 4-(phenylthio)butanenitrile 
• 693-89-0 1-methylcyclopent-1-ene 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 114092-90-9 4-phenylthiobutyl benzoate 
• 3561-67-9 bis(phenylthio)methane 
• 107-02-8 acrolein 
• 98-59-9 p-toluenesulfonyl chloride 
• 93728-00-8 4-(p-Tolylsulfonyloxy-butyl)-phenylsulfid 

Downstream Products

• 115878-51-8 5-Benzenesulfinyl-5-chloro-1-phenylsulfanyl-undecan-4-ol 
• 100231-25-2 7-(phenylthio)hept-1-yn-4-ol 
• 100591-80-8 1-Phenyl-4-phenylsulfanyl-butan-1-ol 
• 90493-74-6 6-phenylthiohex-2-ene 
• 53943-16-1 1,5-bis(phenylthio)pent-1-ene 
• 1612831-31-8 C₂₃H₂₆O₃S 
• 1612831-53-4 methyl 5-hydroxy-2-mesityl-3-oxo-8-(phenylthio)octanoate 
• 100591-81-9 1-Phenylsulfanyl-octan-4-ol 

Relevant articles and documents

Bioinspired Divergent Oxidative Cyclization from Strictosidine and Vincoside Derivatives: Second-Generation Total Synthesis of (?)-Cymoside and Access to an Original Hexacyclic-Fused Furo[3,2-b]indoline

The second-generation synthesis of (?)-cymoside as well as the formation of a new hexacyclic-fused furo[3,2-b]indoline framework is reported. After a Pictet–Spengler condensation between secologanin tetraacetate and tryptamine, the course of the cyclization of the 7-hydroxyindolenine intermediate, generated by oxidation with an oxaziridine, depended on the stereochemistry of the 3-position. The 3-(S)-strictosidine stereochemistry delivered efficiently the scaffold of cymoside via intramolecular coupling with the C16–C17 enol ether, while the 3-(R)-vincoside stereochemistry directed towards the reaction with the C18–C19 terminal alkene and the formation of the unexpected caged compound.

DIHYDROPYRONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME

The present invention provides a compound having an excellent efficacy for controlling weeds. A dihydropyrone compound of formula (I): wherein m is 1, 2 or 3; n is an integer of any one of 1 to 5; X represents O, S, S(O) or S(O)2; R1 /sup

1,5-Hydrogen transfers from carbon to N-tributyltin substituted nitrogen

1,5-H transfers from carbon to N-tributyltin substituted nitrogen proceeded smoothly and were much more efficient than 1,5-H transfers from carbon to ordinary nitrogen. 1,5-Tribuyltin group transfer from carbon to nitrogen and intramolecular addition of an aminyl radical to a nitrile group were also observed for the first time.