77670-31-6

Basic information

• Product Name: Propanedioic acid, methyl(3-oxo-1,3-diphenylpropyl)-, diethyl ester
• CAS NO: 77670-31-6
• Molecular Formula: C23H26O5
• Molecular Weight: 382.456
• Mol File: 77670-31-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, methyl(3-oxo-1,3-diphenylpropyl)-, diethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, methyl(3-oxo-1,3-diphenylpropyl)-, diethyl ester(77670-31-6)
• EPA Substance Registry System: Propanedioic acid, methyl(3-oxo-1,3-diphenylpropyl)-, diethyl ester(77670-31-6)

Safety Data

• Hazardous Substances Data: 77670-31-6(Hazardous Substances Data)

Upstream product

• 609-08-5 Diethyl methylmalonate 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 74-88-4 methyl iodide 
• 77670-30-5 diethyl 2-(3-oxo-1,3-diphenylpropyl)malonate 
• 141-52-6 sodium ethanolate 

Downstream Products

• 609-08-5 Diethyl methylmalonate 
• 614-47-1 1,3-diphenyl-propen-3-one 

Relevant articles and documents

Asymmetric Induction in the Michael Reaction by Means of Chiral Phase-transfer Catalysts derived from Cinchona and Ephedra Alkaloids

Asymmetric induction in the Michael reaction has been achieved using alkaloidonium salts in a two-phase system with optical yields of up to 36 and 26percent in the addition to αβ-unsaturated ketones of thiols and nitroalkanes respectively.The presence of a hydroxy-group β to the 'onium function is essential to achieve substantial asymmetric syntheses.