77693-44-8Relevant academic research and scientific papers
ASYMMETRIC GRIGNARD CROSS-COUPLING BY MEANS OF POLYMER-SUPPORTED OPTICALLY ACTIVE β-DIMETHYLAMINOALKYLPHOSPHINE-NICKEL CATALYSTS
Hayashi, Tamio,Nagashima, Nobuo,Kumada, Makoto
, p. 4623 - 4626 (2007/10/02)
New polymer ligands containing β-dimethylaminoalkylphosphines were prepared using chloromethylated polystyrene, and the ligands were used for nickel-catalyzed asymmetric cross-coupling of sec-alkyl Grignard reagents with vinyl bromide to yield coupling products of ca. 50percent ee.
