77702-44-4

Basic information

• Product Name: p-(4-n-pentylcyclohexyl)-p'-hydroxybiphenyl
• Synonyms: p-(4-n-pentylcyclohexyl)-p'-hydroxybiphenyl
• CAS NO: 77702-44-4
• Molecular Weight: 322.491
• Mol File: 77702-44-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: p-(4-n-pentylcyclohexyl)-p'-hydroxybiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: p-(4-n-pentylcyclohexyl)-p'-hydroxybiphenyl(77702-44-4)
• EPA Substance Registry System: p-(4-n-pentylcyclohexyl)-p'-hydroxybiphenyl(77702-44-4)

Safety Data

• Hazardous Substances Data: 77702-44-4(Hazardous Substances Data)

Upstream product

• 540-38-5 p-Iodophenol 
• 136321-96-5 4-(4-n-pentylcyclohexyl)benzeneboronic acid 

Relevant articles and documents

Ligandless palladium catalyzed reactions of arylboronic acids and sodium tetraphenylborate with aryl halides in aqueous media

Polyfunctional biaryls are prepared by a modified Suzuki cross-coupling reaction between arylboronic acids or sodium tetraphenylborate and aryl halides ArX. X = 1. Br. Cl in aqueous solvents or neat water using a phosphine-free palladium catalyst, and in the presence of bases (Na2CO3 or NaOH). All four phenyl groups of Ph4BNa participate ill the reaction. The reaction of Ph4BNa with aryl halides proceeds in water with high catalytic efficiency (250,000 catalytic cycles).

Reaction of Organoboron Compounds with Organic Halides in Aqueous Media, Catalyzed by "Ligand-Free" Palladium

The results of investigations of the reactions between aryllboric acids or sodium tetraphenylborate and organic halides in water and DMF- and acetone-water mixtures, catalyzed by palladium salts containing no phosphine ligands [Pd(OAc)2, PdCl2], are considered.