777094-95-8

Basic information

• Product Name: 3,5-Cyclohexadiene-1,2-diol, 3-bromo-6-(methylthio)-, (1S,2R)-
• CAS NO: 777094-95-8
• Molecular Formula: C7H9BrO2S
• Molecular Weight: 237.117
• Mol File: 777094-95-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,5-Cyclohexadiene-1,2-diol, 3-bromo-6-(methylthio)-, (1S,2R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Cyclohexadiene-1,2-diol, 3-bromo-6-(methylthio)-, (1S,2R)-(777094-95-8)
• EPA Substance Registry System: 3,5-Cyclohexadiene-1,2-diol, 3-bromo-6-(methylthio)-, (1S,2R)-(777094-95-8)

Safety Data

• Hazardous Substances Data: 777094-95-8(Hazardous Substances Data)

Upstream product

• 104-95-0 (4-bromophenyl)thioanisole 
• 17314-32-8 tributyl(methylthio)stannane 

Downstream Products

• 928122-18-3 (1S,6S)-6-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2-methylsulfanyl-cyclohex-2-enol 
• 898235-75-1 (1R,2S)-2-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-cyclohexanol 
• 793697-46-8 (1S,2S)-3-(methylsulfanyl)cyclohex-5-ene-1,2-diol 
• 138769-97-8 (1S,2S)-1,2-dihydroxy-3-methylsulfanylcyclohexa-3,5-diene 

Relevant articles and documents

Enzymatic oxidation of thioanisoles: Isolation and absolute configuration of metabolites

Oxidation of p-bromothioanisole with toluene dioxygenase provides the corresponding diene diol 2 in good yield. Electrochemical reduction of 2 gives access to diene diol 3, which is not accessible by direct bio-oxidation of thioanisole. Absolute configura

Toluene dioxygenase-mediated oxidation of bromo(methylsulfanyl)benzenes. Absolute configuration of metabolites and evaluation of chemo- and regioselectivity trends

A series of 2-, 3-, and 4-bromo-1-(methylsulfanyl)benzenes was subjected to whole-cell fermentation with Escherichia coli JM 109 (pDTG601), a recombinant strain that expresses toluene dioxygenase. New metabolites were isolated and their structure and abso