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Ammonium sulfamate, also known as monoammonium sulfamate, is an inorganic compound with the chemical formula NH4NSO3H or NH4SO3NH2. It is a white crystalline solid that is soluble in water and has a slightly acidic pH. Ammonium sulfamate is a versatile chemical with a wide range of applications in various industries.

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  • 7773-06-0 Structure
  • Basic information

    1. Product Name: Ammonium sulfamate
    2. Synonyms: SULFAMIC ACID AMMONIUM SALT;AMIDOSULFONIC ACID AMMONIUM SALT;AMINOSULFONIC ACID AMMONIUM SALT;AMMONIUM SULFAMATE;AMMONIUM SULPHAMATE;AMMONIUM AMIDOSULFATE;AMMONIUM AMIDOSULFONATE;AMMONIUM AMIDOSULPHATE
    3. CAS NO:7773-06-0
    4. Molecular Formula: H6N2O3S
    5. Molecular Weight: 114.12
    6. EINECS: 231-871-7
    7. Product Categories: Intermediates of Dyes and Pigments;Inorganics;BioUltraPesticides&Metabolites;Herbicides;Molecular Biology;Molecular Biology Reagents;Ammonium;Inorganic Salts;Synthetic Reagents;ACS GradeSynthetic Reagents;Essential Chemicals;Routine Reagents;A-B, Puriss p.a.Pesticides&Metabolites;Analytical Reagents for General Use;Puriss p.a.;fine chemicals;Piperidines
    8. Mol File: 7773-06-0.mol
  • Chemical Properties

    1. Melting Point: 131-135 °C(lit.)
    2. Boiling Point: 160°C
    3. Flash Point: 160°C
    4. Appearance: White/Crystalline Powder
    5. Density: 1.8 g/cm3
    6. Vapor Pressure: 0Pa at 20℃
    7. Refractive Index: N/A
    8. Storage Temp.: Store at RT.
    9. Solubility: H2O: 1 M at 20 °C, clear, colorless
    10. Water Solubility: 1950 g/L (20 ºC)
    11. Sensitive: Air & Moisture Sensitive
    12. Stability: Stable. Incompatible with strong acids, strong oxidizing agents.
    13. Merck: 14,554
    14. CAS DataBase Reference: Ammonium sulfamate(CAS DataBase Reference)
    15. NIST Chemistry Reference: Ammonium sulfamate(7773-06-0)
    16. EPA Substance Registry System: Ammonium sulfamate(7773-06-0)
  • Safety Data

    1. Hazard Codes: Xn,N
    2. Statements: 22-50
    3. Safety Statements: 24/25-22-61
    4. RIDADR: UN 3077 9/PG 3
    5. WGK Germany: 1
    6. RTECS: WO6125000
    7. F: 3-10
    8. TSCA: Yes
    9. HazardClass: N/A
    10. PackingGroup: III
    11. Hazardous Substances Data: 7773-06-0(Hazardous Substances Data)

7773-06-0 Usage

Uses

Used in Fire-Retardant Compositions:
Ammonium sulfamate is used as a flame retardant for textiles and paper products. It helps to slow down the spread of fire and reduce the risk of damage caused by flames.
Used in Weed Killing Compositions:
Ammonium sulfamate is used as an inorganic herbicide for the control of woody plants and herbaceous perennials. It is effective in eliminating unwanted vegetation and promoting the growth of desired plants.
Used in Electroplating Solutions:
Ammonium sulfamate is used in electroplating solutions to improve the quality and appearance of the plated metal surface. It enhances the adhesion and uniformity of the metal coating, resulting in a smoother and more durable finish.
Used in the Generation of Nitrous Oxide Gas:
Ammonium sulfamate is used as a precursor in the production of nitrous oxide gas. It is a key component in the chemical reactions that generate this gas, which has various industrial and medical applications.

Air & Water Reactions

Water soluble. Hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid)] .

Reactivity Profile

Ammonium sulfamate is incompatible with the following: Acids, hot water [Note: Elevated temperatures cause a highly exothermic reaction with water (in the presence of acid).] .

Hazard

Hot acid solutions when enclosed may explode.

Health Hazard

Inhalation causes irritation of nose and throat. Ingestion causes gastrointestinal disturbances. Dust irritates eyes.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Somewhat explosive when heated or by spontaneous chemical reaction in a hot acid solution. A powerful oxidizer. When heated to decomposition it emits very toxic fumes of NH3, NOx, and SOx. See also SULFONATES and SULFAMIC ACID.

Potential Exposure

Ammonium sulfamate is used as a herbicide and in compositions for retarding flame in textiles and paper products; a softener for paper, cotton textiles.

Carcinogenicity

The oral LD50 values were 3900 mg/kg for rats and 5760 mg/kg for mice.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Purification Methods

Crystallise it from water at room temperature (1mL/g) by adding EtOH and cooling. [Sisler & Audrieth Inorg Synth II 180 1946.]

Incompatibilities

Strong oxidizers, potassium, potassium chlorate, sodium nitrite, metal chlorates, and hot acid solutions. Elevated temperatures cause a highly exothermic reaction with water.

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Dilute with water, make neutral with acid or base and flush into sewer with more water.

Check Digit Verification of cas no

The CAS Registry Mumber 7773-06-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,7 and 3 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 7773-06:
(6*7)+(5*7)+(4*7)+(3*3)+(2*0)+(1*6)=120
120 % 10 = 0
So 7773-06-0 is a valid CAS Registry Number.
InChI:InChI=1/H3NO3S/c1-5(2,3)4/h(H3,1,2,3,4)/p-1

7773-06-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (A17696)  Ammonium sulfamate, 98+%   

  • 7773-06-0

  • 250g

  • 215.0CNY

  • Detail
  • Alfa Aesar

  • (A17696)  Ammonium sulfamate, 98+%   

  • 7773-06-0

  • 1000g

  • 655.0CNY

  • Detail
  • Alfa Aesar

  • (14534)  Ammonium sulfamate, ACS, 98% min   

  • 7773-06-0

  • 500g

  • 675.0CNY

  • Detail
  • Alfa Aesar

  • (14534)  Ammonium sulfamate, ACS, 98% min   

  • 7773-06-0

  • 2kg

  • 2361.0CNY

  • Detail
  • Sigma-Aldrich

  • (228745)  Ammoniumsulfamate  ACS reagent, ≥98.0%

  • 7773-06-0

  • 228745-100G

  • 358.02CNY

  • Detail
  • Sigma-Aldrich

  • (228745)  Ammoniumsulfamate  ACS reagent, ≥98.0%

  • 7773-06-0

  • 228745-500G

  • 1,075.23CNY

  • Detail
  • Fluka

  • (09960)  Ammoniumsulfamate  puriss. p.a., ≥99.0% (T)

  • 7773-06-0

  • 09960-100G

  • 336.96CNY

  • Detail
  • Honeywell

  • (09970)  Ammoniumsulfamate  purum p.a., ≥98.0% (NT)

  • 7773-06-0

  • 09970-1KG

  • 1,512.81CNY

  • Detail
  • Sigma-Aldrich

  • (A2585)  Ammoniumsulfamate  BioXtra, ≥98.0%

  • 7773-06-0

  • A2585-25G

  • 331.11CNY

  • Detail
  • Sigma-Aldrich

  • (A2585)  Ammoniumsulfamate  BioXtra, ≥98.0%

  • 7773-06-0

  • A2585-100G

  • 730.08CNY

  • Detail
  • Vetec

  • (V900045)  Ammoniumsulfamate  Vetec reagent grade, 98%

  • 7773-06-0

  • V900045-100G

  • 59.67CNY

  • Detail

7773-06-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name ammonium sulfamate

1.2 Other means of identification

Product number -
Other names ammonium sulphamate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7773-06-0 SDS

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