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7773-06-0

Basic Information
CAS No.: 7773-06-0
Name: Ammonium sulfamate
Molecular Structure:
Molecular Structure of 7773-06-0 (Ammonium sulfamate)
Formula: H6N2O3S
Molecular Weight: 114.14
Synonyms: Sulfamicacid, monoammonium salt (8CI,9CI);AMS;AMS (salt);Ammat;Ammate;Ammate X;Ammonium amidosulfate;Ammonium amidosulfonate;Ammonium amidosulphate;Ammonium aminosulfonate;Ammonium sulfamate;Ammonium sulphamate;Feliderm K;Fyran 206K;Fyran J 3;Ikurin;Monoammonium sulfamate;
EINECS: 231-871-7
Density: 1.8 g/cm3
Melting Point: 131 °C
Boiling Point: 160 °C
Flash Point: 160oC
Solubility: very soluble in water, and insoluble in methanol, ether, n-octanol
Appearance: White solid
Hazard Symbols: HarmfulXn
Risk Codes: 22
Safety: 24/25-22
Transport Information: UN 3077 9/PG 3
PSA: 91.60000
LogP: 0.56260
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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 10 mg/m3; Respirable Fraction: 5 mg/m3
ACGIH TLV: TWA 10 mg/m3
DFG MAK: 15 mg/m3

Specification

The Ammonium sulfamate, with the CAS registry number 7773-06-0 and EINECS registry number 231-871-7, is also known as AMS. It is a kind of white crystalline solid which is readily soluble in water, and it will decompose when the temperature is higher than 160 °C. And the molecular formula of this chemical is H6N2O3S. It is commonly used as a broad spectrum herbicide, with additional uses as a compost accelerator.

Physical properties about Ammonium sulfamate are: (1)ACD/LogP: -1.416; (2)ACD/LogD (pH 5.5): -4.86; (3)ACD/LogD (pH 7.4): -4.92; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors: 4; (7)#H bond donors: 3

Synthesis and uses of Ammonium sulfamate: Dissolve purificatory amidosulphuric acid in the liquid ammonia, and left to stand until unreacted ammonia evaporated, the left thing is ammonium sulfamate. Ammonium sulfamate is usually used as a broad spectrum herbicide which is particularly useful in controlling tough woody weeds, tree stumps and brambles. And it is also used as a flame retardant, a plasticiser and in electro-plating in industry.

You should be cautious while dealing with this chemical. It is harmful if swallowed. Therefore, you had better take the following instructions: Do not breathe dust and try to avoid contacting with skin and eyes.

You can still convert the following datas into molecular structure:
(1)SMILES: [O-]S(=O)(=O)N.[NH4+]
(2)InChI: InChI=1/H3NO3S.H3N/c1-5(2,3)4;/h(H3,1,2,3,4);1H3
(3)InChIKey: GEHMBYLTCISYNY-UHFFFAOYAI

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD intraperitoneal > 500mg/kg (500mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 316, 1952.
mouse LD50 oral 3100mg/kg (3100mg/kg) BEHAVIORAL: GENERAL ANESTHETIC

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 7(5), Pg. 56, 1963.
rat LD50 oral 2gm/kg (2000mg/kg)   AMA Archives of Industrial Health. Vol. 14, Pg. 178, 1956.
rat LDLo intraperitoneal 800mg/kg (800mg/kg) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 26, 1943.