77758-84-0 Usage
Uses
Used in Synthetic Chemistry:
(Perfluoro-n-hexyl)phenyliodonium trifluoromethanesulfonate is used as a building block for synthetic fluoroalkylations due to its unique structure and reactivity. It plays a crucial role in the synthesis of various fluorinated compounds, which have a wide range of applications in different industries, including pharmaceuticals, agrochemicals, and materials science.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (Perfluoro-n-hexyl)phenyliodonium trifluoromethanesulfonate is used as a key intermediate in the synthesis of fluorinated drug candidates. The introduction of fluorine atoms into drug molecules can significantly improve their pharmacokinetic and pharmacodynamic properties, such as increasing their lipophilicity, metabolic stability, and bioavailability.
Used in Agrochemical Industry:
(Perfluoro-n-hexyl)phenyliodonium trifluoromethanesulfonate is also utilized in the agrochemical industry for the synthesis of fluorinated pesticides and agrochemicals. Fluorinated compounds often exhibit enhanced biological activity and selectivity, making them valuable for the development of more effective and environmentally friendly pesticides.
Used in Materials Science:
In the field of materials science, (Perfluoro-n-hexyl)phenyliodonium trifluoromethanesulfonate is employed in the synthesis of fluorinated polymers and materials with unique properties, such as improved thermal stability, chemical resistance, and non-stick characteristics. These materials find applications in various industries, including electronics, automotive, and aerospace.
Check Digit Verification of cas no
The CAS Registry Mumber 77758-84-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,7,5 and 8 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 77758-84:
(7*7)+(6*7)+(5*7)+(4*5)+(3*8)+(2*8)+(1*4)=190
190 % 10 = 0
So 77758-84-0 is a valid CAS Registry Number.
InChI:InChI=1/C12H5F13I.CHF3O3S/c13-7(14,9(17,18)11(21,22)23)8(15,16)10(19,20)12(24,25)26-6-4-2-1-3-5-6;2-1(3,4)8(5,6)7/h1-5H;(H,5,6,7)/q+1;/p-1
77758-84-0Relevant academic research and scientific papers
[Hydroxy(sulfonyloxy)iodo]perfluoroalkanes: New and convenient reagents for the preparation of fluoroalkyl(aryl)iodonium salts
Kuehl,Bolz,Zhdankin
, p. 312 - 316 (2007/10/02)
[Hydroxy(sulfonyloxy)iodo]perfluoroalkanes (C(n)F(2n+1) I+ OH · - OSO2 R, n = 2,3,4,6,8; R = Me,p-MeC6H4,CF3) can be prepared in two steps from the corresponding perfluoroalkyliodides by ox
perfluoroalkanes - New Hypervalent Iodine Species and Promising Reagents for Organic Synthesis
Zhdankin, Viktor V.,Kuehl, Chris
, p. 1809 - 1812 (2007/10/02)
perfluoroalkanes (CnF(2n+1)I(1+)OH*(1-)OSO2R, n=3, 4, 6; R=p-CH3C6H4, CF3) can be prepared in two steps from the corresponding perfluoroalkyliodides by oxidation with pertrifluoroacetic acid and subsequent reaction with TsOH or M
Perfluoroalkyl compounds and process for preparing the same
-
, (2008/06/13)
Perfluoroalkyl compounds represented by the formula (I): STR1 wherein Rf represents a perfluoroalkyl group having 1 to 20 carbon atoms, Ar represents a substituted or unsubstituted phenyl group wherein the substituent is an alkyl group having 1 to 4 carbon atoms or a halogen atom, I represents an iodine atom, and A represents a perfluoroalkyl group having 1 to 20 carbon atoms which can be the same or different from Rf, a hydroxy group an alkyl group having 1 to 4 carbon atoms, an aryl group or a halogen atom, and processes for preparing the perfluoroalkyl compounds represented by the formula (I).
