77758-84-0

Basic information

• Product Name: (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE
• Synonyms: (Tridecafluorohexyl)phenyliodonium Trifluoromethanesulfonate;Phenyl(tridecafluorohexyl)iodonium·trifluoromethanesulfonate;(PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE;perfluorohexylphenyliodoniumtrifluoromethanesulfonate
• CAS NO: 77758-84-0
• Molecular Formula: CF₃O₃S*C₁₂H₅F₁₃I
• Molecular Weight: 672.12
• Product Categories: Fits Reagents;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Fluorous Chemistry;Fluorous Compounds;Hypervalent Iodine Compounds;Perfluroalkylation;Synthetic Organic Chemistry
• Mol File: 77758-84-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 120.0 to 126.0 °C
• Appearance: /
• Storage Temp.: Refrigerator
• CAS DataBase Reference: (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE(CAS DataBase Reference)
• NIST Chemistry Reference: (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE(77758-84-0)
• EPA Substance Registry System: (PERFLUORO-N-HEXYL)PHENYLIODONIUM TRIFLUOROMETHANESULFONATE(77758-84-0)

Safety Data

• Hazardous Substances Data: 77758-84-0(Hazardous Substances Data)

Usage

Uses

(Perfluorohexyl)phenyliodonium trifluoromethanesulfonate (CAS# 77758-84-0) is a useful building block used in synthetic fluoroalkylations.

InChI:InChI=1/C12H5F13I.CHF3O3S/c13-7(14,9(17,18)11(21,22)23)8(15,16)10(19,20)12(24,25)26-6-4-2-1-3-5-6;2-1(3,4)8(5,6)7/h1-5H;(H,5,6,7)/q+1;/p-1

Upstream product

• 13183-70-5 1,4-bis-(trimethylsilyl)benzene 
• 155819-13-9 perfluorohexane 
• 34060-68-9 [bis(trifluoroacetoxy)]tridecafluoro-6-iodohexane 
• 355-43-1 n-perfluorohexyl iodide 
• 768-32-1 trimethylphenylsilane 

Downstream Products

• 56734-76-0 α-tridecafluorohexylcyclohexanone 
• 65440-93-9 (tridecafluorohexyl)benzene 

Relevant articles and documents

[Hydroxy(sulfonyloxy)iodo]perfluoroalkanes: New and convenient reagents for the preparation of fluoroalkyl(aryl)iodonium salts

[Hydroxy(sulfonyloxy)iodo]perfluoroalkanes (C(n)F(2n+1) I+ OH · - OSO2 R, n = 2,3,4,6,8; R = Me,p-MeC6H4,CF3) can be prepared in two steps from the corresponding perfluoroalkyliodides by ox

Perfluoroalkyl compounds and process for preparing the same

Perfluoroalkyl compounds represented by the formula (I): STR1 wherein Rf represents a perfluoroalkyl group having 1 to 20 carbon atoms, Ar represents a substituted or unsubstituted phenyl group wherein the substituent is an alkyl group having 1 to 4 carbon atoms or a halogen atom, I represents an iodine atom, and A represents a perfluoroalkyl group having 1 to 20 carbon atoms which can be the same or different from Rf, a hydroxy group an alkyl group having 1 to 4 carbon atoms, an aryl group or a halogen atom, and processes for preparing the perfluoroalkyl compounds represented by the formula (I).