77803-76-0

Basic information

• Product Name: 2-Oxa-3-azabicyclo[2.2.2]oct-5-ene, 3-acetyl- (9CI)
• Synonyms: 2-Oxa-3-azabicyclo[2.2.2]oct-5-ene, 3-acetyl- (9CI)
• CAS NO: 77803-76-0
• Molecular Formula: C8H11NO2
• Molecular Weight: 153.17844
• Product Categories: ACETYLGROUP
• Mol File: 77803-76-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 210.9±43.0 °C(Predicted)
• Appearance: /
• Density: 1.181±0.06 g/cm3(Predicted)
• PKA: -1.52±0.20(Predicted)
• CAS DataBase Reference: 2-Oxa-3-azabicyclo[2.2.2]oct-5-ene, 3-acetyl- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxa-3-azabicyclo[2.2.2]oct-5-ene, 3-acetyl- (9CI)(77803-76-0)
• EPA Substance Registry System: 2-Oxa-3-azabicyclo[2.2.2]oct-5-ene, 3-acetyl- (9CI)(77803-76-0)

Safety Data

• Hazardous Substances Data: 77803-76-0(Hazardous Substances Data)

Upstream product

• 546-88-3 acetylhydroxamic acid 
• 1165952-91-9 cyclohexa-1,3-diene 
• 63115-45-7 nitrosocarbonylmethane 
• 108-24-7 acetic anhydride 
• 56239-25-9 2-Oxa-3-azabicyclo<2.2.2>oct-5-ene hydrochloride 
• 683-58-9 acetohydroximoyl chloride 

Downstream Products

• 87013-23-8 N-acetyl-2-oxa-3-azabicyclo<2.2.2>octane 

Relevant articles and documents

Photocatalyzed Generation of Nitrosocarbonyl Intermediates Under Solar Light Irradiation

Tetrabutylammonium decatungstate (TBADT) has emerged as a valuable photocatalyst for sunlight-induced organic reactions. In this communication we wish to present its use for the photocatalytic oxidation of hydroxamic acids to generate fleeting nitrosocarb

Straightforward hetero Diels-Alder reactions of nitroso dienophiles by microreactor technology

The hetero Diels-Alder reactions of 2-nitrosotoluene and some representative acylnitrosodienophiles with a selected set of 1,3-dienes were studied under microflow conditions. The main assets of the technology, that is, an accurate control of the reaction

Generation of acyl nitroso compounds by the oxidation of N-acyl hydroxylamines with the Dess-Martin periodinane

The oxidation of hydroxamic acids, N-hydroxyureas and N- hydroxycarbamates with the Dess-Martin periodinane generates the corresponding acyl nitroso compounds that react with conjugated dienes to produce the corresponding cycloadducts.