77803-76-0Relevant academic research and scientific papers
Photocatalyzed Generation of Nitrosocarbonyl Intermediates Under Solar Light Irradiation
Basile, Teresa,Capaldo, Luca,Ravelli, Davide,Quadrelli, Paolo
, p. 1443 - 1447 (2019/06/08)
Tetrabutylammonium decatungstate (TBADT) has emerged as a valuable photocatalyst for sunlight-induced organic reactions. In this communication we wish to present its use for the photocatalytic oxidation of hydroxamic acids to generate fleeting nitrosocarb
Copper-catalyzed aerobic oxidation of N-substituted hydroxylamines: Efficient and practical access to nitroso compounds
Frazier, Charles P.,Bugarin, Alejandro,Engelking, Jarred R.,Read De Alaniz, Javier
experimental part, p. 3620 - 3623 (2012/09/08)
A general and efficient aerobic oxidation of N-substituted hydroxylamines is described. The mild reaction conditions employed provide a catalytic and sustainable alternative to stoichiometric oxidation methods to gain access to a range of nitroso compound
Straightforward hetero Diels-Alder reactions of nitroso dienophiles by microreactor technology
Monbaliu, Jean-Christophe M.R.,Cukalovic, Ana,Marchand-Brynaert, Jacqueline,Stevens, Christian V.
experimental part, p. 5830 - 5833 (2010/12/20)
The hetero Diels-Alder reactions of 2-nitrosotoluene and some representative acylnitrosodienophiles with a selected set of 1,3-dienes were studied under microflow conditions. The main assets of the technology, that is, an accurate control of the reaction
Synthesis of 1,2- and 1,4-amino alcohols from 1,3-dienes via oxazines. Rearrangements of 1,4-amino alcohol derivatives to oxazolines
Werner, Lukas,Hudlicky, Jason Reed,Wernerova, Martina,Hudlicky, Tomas
experimental part, p. 3761 - 3769 (2010/07/05)
Conjugated dienes were converted to 1,2-oxazines by reaction with an acyl nitroso dienophile. The oxazines were reduced to 1,4-N-acetylamino alcohols, which were rearranged to the corresponding oxazolines upon treatment with methanesulfonyl chloride or an
Generation of acyl nitroso compounds by the oxidation of N-acyl hydroxylamines with the Dess-Martin periodinane
Jenkins, Neil E.,Ware Jr., Roy W.,Atkinson, Robert N.,King, S. Bruce
, p. 947 - 953 (2007/10/03)
The oxidation of hydroxamic acids, N-hydroxyureas and N- hydroxycarbamates with the Dess-Martin periodinane generates the corresponding acyl nitroso compounds that react with conjugated dienes to produce the corresponding cycloadducts.
The mild oxidation of nitrile oxides affords a convenient entry to nitrosocarbonyl intermediates, versatile tools in organic syntheses
Quadrelli,Mella,Gamba Invernizzi,Caramella
, p. 10497 - 10510 (2007/10/03)
Nitrile oxides are oxidized by tertiary amine N-oxides in different solvents at room temperature to afford in the presence of dienes nitrosocarbonyl adducts in fair yields. The mild conditions used in oxidizing a variety of nitrile oxides promise a wide application of this method in synthetic processes.
A mild oxidation of nitrile oxides: A new synthetic route to nitroso carbonyl intermediates
Quadrelli,Gamba Invernizzi,Caramella
, p. 1909 - 1912 (2007/10/03)
Addition of N-methyl morpholine N-oxide (NMO) to a nitrile oxide solution in dichloromethane at room temperature in the presence of a diene affords nitroso carbonyl adducts in fair yields.
