778593-54-7Relevant academic research and scientific papers
Synthesis, photophysics and molecular structures of luminescent 2,5-bis(phenylethynyl)thiophenes (BPETs)
Siddle, Jamie S.,Ward, Richard M.,Collings, Jonathan C.,Rutter, Simon R.,Porres, Laurent,Applegarth, Lucas,Beeby, Andrew,Batsanov, Andrei S.,Thompson, Amber L.,Howard, Judith A. K.,Boucekkine, Abdou,Costuas, Karine,Halet, Jean-Francois,Marder, Todd B.
, p. 841 - 851 (2008/02/12)
The Sonogashira cross-coupling of two equivalents of para-substituted ethynylbenzenes with 2,5-diiodothiophene provides a simple synthetic route for the preparation of 2,5-bis(para-R-phenylethynyl)thiophenes (R = H, Me, OMe, CF3, NMe2/sub
Synthesis of conjugated 2 and 2,5-(ethenyl) and (ethynyl)phenylethynyl thiophenes: Fluorescence properties
Rodriguez, J. Gonzalo,Esquivias, Jorge,Lafuente, Antonio,Rubio, Laura
, p. 3112 - 3122 (2007/10/03)
Nano conjugated thienylethenyl and thienylethynyl compounds with controlled structure and dimensions have been efficiently prepared, by heterocoupling reaction between 1,4-(thienylethynyl)phenylacetylene (or thienylethenyl) phenylacetylene and 2- or 2,5-dihalothiophene. Conjugated 1,4-di(2- thienylethynylphenyl)- (or 2-thienylethenylphenyl)-1,3-butadiyne were obtained by the homocoupling of the terminal acetylenes in excellent yield. The end-capped (N,N-dimethylaminophenyl)- and [3,5-di(trimethylsilylethynyl)-1- ethynyl]-2,5-di(phenylethynyl)nthiophene were obtained by the heterocoupling between the corresponding terminal acetylene and 2,5-di(iodo)thiophene, catalyzed by the bis(triphenylphosphine)palladium and cuprous iodide system in excellent yield.
Synthesis and optical properties of conjugated N,N-dimethyl and thienyl end-capped 2,5-(arylethynyl)thiophene oligomer structures
Rodríguez, J. Gonzalo,Lafuente, Antonio,Rubio, Laura,Esquivias, Jorge
, p. 7061 - 7064 (2007/10/03)
End-capped (N,N-dimethylaminophenyl) and 2′-thienylethynyl 2,5-thiophene oligomer structures were synthesized by heterocoupling between the terminal acetylenes such as: p-(N,N-dimethylaminophenyl)ethyne (3) [or 1-(p-(N,N-dimethylaminophenyl)-2-p-(ethynylp
