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77863-85-5

77863-85-5

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77863-85-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 77863-85-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,7,8,6 and 3 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 77863-85:
(7*7)+(6*7)+(5*8)+(4*6)+(3*3)+(2*8)+(1*5)=185
185 % 10 = 5
So 77863-85-5 is a valid CAS Registry Number.

77863-85-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name benzyl (N-benzyl-p-chlorobenzamido)methylsulfide

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:77863-85-5 SDS

77863-85-5Downstream Products

77863-85-5Relevant articles and documents

NOVEL REARRANGEMENTS OF α-N-ALKYLAMIDO-SUBSTITUTED SULFIDES AND SULFONES

Ishikawa, Yoshiharu,Kurebayashi, Yasuo,Suzuki, Kunio,Terao, Yoshiyasu,Sekiya, Minoru

, p. 2496 - 2502 (2007/10/02)

The present paper describes novel rearrangements of α-N-alkylamido-substituted sulfides and sulfones promoted by strong bases such as NaH, lithium diisopropylamide and butyllithium, where the alkyl group linked to the sulfur migrates to the amide carbonyl carbon to give the corresponding ketones.The reactions are established as intramolecular rearrangements, and the mechanism is discussed.Keywords: - alkyl (N-alkylamido)methyl sulfide; alkyl (N-alkylamido)methyl sulfone; alkyl α-(N-alkylamido)benzyl sulfide; intramolecular rearrangement; sodium hydride; lithium diisopropylamide; butyllithium

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