77873-64-4Relevant academic research and scientific papers
A NOVEL SYNTHETIC METHOD FOR γ-ACETOXY-(E)-α,β-UNSATURATED ESTERS BY THE PALLADIUM CATALYZED REGIO- AND STEREOSELECTIVE ACETOXYLATION OF β,γ-UNSATURATED ESTERS
Tsuji, Jiro,Sakai, Kiyomi,Nagashima, Hideo,Shimizu, Isao
, p. 131 - 134 (1981)
A new synthetic method for γ-acetoxy-α,β-unsaturated esters by the acetoxylation of β,γ-unsaturated esters catalyzed by PdCl2 in the presence of KOAc and pentyl nitrite in acetic acid is presented.The reaction takes place at γ-position of the esters regio
