53723-52-7

Basic information

• Product Name: (1-Cyclohexenyl)acetic acid methyl ester
• Synonyms: (1-Cyclohexenyl)acetic acid methyl ester;1-Cyclohexene-1-acetic acid methyl ester
• CAS NO: 53723-52-7
• Molecular Formula: C₉H₁₄O₂
• Molecular Weight: 154.21
• Mol File: 53723-52-7.mol
• Article Data: 11

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (1-Cyclohexenyl)acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1-Cyclohexenyl)acetic acid methyl ester(53723-52-7)
• EPA Substance Registry System: (1-Cyclohexenyl)acetic acid methyl ester(53723-52-7)

Safety Data

• Hazardous Substances Data: 53723-52-7(Hazardous Substances Data)

Upstream product

• 186581-53-3 diazomethane 
• 18294-87-6 1-cyclohexenylacetic acid 
• 17497-53-9 1-iodo-1-cyclohexene 
• 67-56-1 methanol 
• 931-49-7 1-ethenylcyclohexene 
• 86769-61-1 ((1R,2S)-2-Phenylsulfanyl-cyclohexyl)-acetic acid methyl ester 
• 14032-03-2 ((1R,2R)-2-chlorocyclohexyl)(phenyl)sulfane 
• 108-94-1 cyclohexanone 
• 110-83-8 cyclohexene 
• 6975-71-9 1-cyclohexenylacetonitrile 
• 124-41-4 sodium methylate 
• 40203-74-5 methyl 2-cyclohexylideneacetate 
• 201230-82-2 carbon monoxide 
• 1192-37-6 methylenecyclohexane 

Downstream Products

• 76519-80-7 1-(1-cyclohexenyl)-2-methyl-2-propanol 
• 77873-64-4 (6-Acetoxy-cyclohex-1-enyl)-acetic acid methyl ester 
• 3197-68-0 2-(1-Cyclohexenyl)ethanol 
• 55751-36-5 perfluoro(7-oxabicyclo<4.3.0>nonane) 
• 74317-65-0 perfluoro(cyclohexylacetyl fluoride) 
• 74179-30-9 perfluoro(8-methoxy-7-oxabicyclo<4.3.0>nonane) 
• 1439386-60-3 C₁₀H₁₆O 
• 1439386-86-3 C₁₇H₂₂O₂ 
• 75526-59-9 (3aS,7aR)-3a-Phenylselanyl-octahydro-benzofuran 
• 113404-54-9 5-(1-cyclohexenyl)bicyclo<3.2.0>heptan-6-one 
• 4065-80-9 2-methylenecyclohexanol 
• 83321-29-3 2-(1-cyclohexenyl)ethyl brosylate 
• 389607-98-1 5-(1-cyclohexenyl)-pentanophenone N,N-dimethylhydrazone 
• 389608-00-8 4-(1-cyclohexenyl)-butyrophenone N,N-dimethylhydrazone 

Relevant articles and documents

The total syntheses of basiliolide C, epi-basiliolide C, and protecting-group-free total syntheses of transtaganolides C and D

The total syntheses of basiliolide C and previously unreported epi-basiliolide C are achieved by an Ireland-Claisen/Diels-Alder cascade. The development of a palladium catalyzed cross-coupling of methoxy alkynyl zinc reagents allows for the protecting-group-free syntheses of transtaganolides C and D. Syntheses of transtaganolides C and D are accomplished in a single operation to generate three rings, two all-carbon quaternary centers, and four tertiary stereocenters from a monocyclic, achiral precursor. (Chemical Equation Presented).

Rhodium-catalyzed oxygenative addition to terminal alkynes for the synthesis of esters, amides, and carboxylic acids

A gem of a couple: The title reaction of terminal alkynes with O and Nnucleophiles proceeds in the presence of [Rh(cod)Cl}2], P(4-FC 6H4)3, and 4-picoline N-oxide. Alcohols, amines, and water add to the terminal alkynes to give esters, amides, and carboxylic acids, respectively. The reaction involves formation of a rhodium vinylidene, oxidation to a ketene by oxygen transfer, and nucleophilic addition.

Asymmetric dihydroxylation of β,γ-unsaturated carboxylic esters with trisubstituted C=C bonds - Enantioselective syntheses of trisubstituted γ-butyrolactones

β,γ-Unsaturated esters with stereodefined trisubstitued C=C double bonds were prepared by the Arndt-Eistert homologation of α,β-unsaturated carboxyl halides, by two-step methoxycarbonylation of allylbarium reagents, by deconjugation of α,β-unsaturated esters, and by Horner-Wadsworth-Emmons variants of the Stobbe condensation. Sharpless asymmetric dihydroxylation of the β,γ-unsaturated esters, followed by spontaneous cyclization, afforded β-hydroxy-γ-lactones in moderate to good yields and with enantiomeric excesses of up to 97 %. Similarly, tetrahydroxy-γ-lactones were obtained from diunsaturated esters; these lactones were converted into a bislactone and an unsaturated β-hydroxy γ-lactone. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.