77874-38-5

Upstream product

• 67-56-1 methanol 
• 138811-45-7 1,2,3,5,6-penta-O-benzoyl-D-galactofuranose 
• 226211-26-3 O-(2,3,5,6-tetra-O-benzoyl-β-D-galactofuranosyl)-trichloroacetimidate 

Downstream Products

• 223131-29-1 dimethyl C-(2,3,5,6-tetra-O-benzyl-α-D-galactofuranosyl)methanephosphonate 
• 116444-18-9 C-(2,3,5,6-tetra-O-benzyl-α-D-galactofuranosyl)iodomethane 
• 116444-14-5 3,4,6,7-tetra-O-benzyl-1,2-dideoxy-d-galacto-hept-1-enitol 
• 89539-39-9 2,3,5,6-tetra-O-benzyl-α/β-D-galactofuranose 
• 18685-21-7 methyl 2,3,5,6-tetra-O-benzyl-β-D-galactofuranoside 

Relevant academic research and scientific papers

Differential O-3/O-4 regioselectivity in the glycosylation of α and β anomers of 6-O-substituted N-dimethylmaleoyl-protected d-glucosamine acceptors

An assessment of the relative O-3/O-4 reactivities of both methyl α- and β-d-glycosides of N-dimethylmaleoyl (DMM) d-glucosamine acceptors protected at O-6 with benzoyl (Bz), benzyl (Bn), and tert-butyldiphenylsilyl (TBDPS) groups is presented using per-O

SYNTHESIS OF GALACTOFURANOSE DISACCHARIDES OF BIOLOGICAL SIGNIFICANCE

Methyl β-D-galactofuranoside (3) was readily obtained by tin(IV) chloride-catalyzed glycosylation of penta-O-benzoyl-α,β-D-galactofuranose (1), followed by debenzoylation with sodium methoxide.Glycosylation of 1 with 2,3,5-tri-O-benzoyl-D-galactono-1,4-la