77893-59-5Relevant articles and documents
A Carbon-13 Nuclear Magnetic Resonance Study of Compounds Substituted by a Perfluoroalkyl Chain
Tordeux, M.,Leroy, J.,Wakselman, C.
, p. 407 - 409 (1980)
The 13C NMR spectra of alkanes, alkanones and cyclohexanones substituted by perfluoroalkyl groups, RF, have been studied.The influence of the perfluoroalkyl group on the chemical shifts of other carbons of the molecules is the same regardless of the RF chain length.
ELECTROCHEMICAL SYNTHESIS OF PERFLUOROALKYLACETONES
Vol'pin, I. M.,Kurykin, M. A.,Grinberg, V. A.,Vasil'ev, Yu. B.,German, L. S.
, p. 1395 - 1400 (2007/10/02)
The interaction of electrochemically generated radicals in the electrolysis of the perfluorocarboxylic acids RFCF2COOH (I), where RF = F (a), CF3 (b), C2F5 (c), C3F7 (d), C5F11 (e). and C7F15 (f), with isoprenyl acetate (II) was studied.The dependence of the results of the electrolysis on the adsorption capacity of the anode permits the proposition that the interaction of (II) with the ECG-radicals occurs close to the surface of the electrode.The yield of the perfluoroalkylacetones comprised 30-37percent.
Annelation d'enamines par les cetones α,β-ethyleniques fluorees. VI (1): Reaction d'aromatisation
Molines, Huguette,Tordeux, Marc,Wakselman, Claude
, p. 367 - 368 (2007/10/02)
Various perfluoroalkylacetones were prepared by addition of perfluoroalkyliodides to 2-methoxypropene and condensed with 1-pyrrolidinocyclopentene or -cyclohexene.An annelation-aromatisation process led to 4-perfluoroalkyl-6-pyrrolidinoindanes and 1-perfluoroalkyl-3-pyrrolidino-5,6,7,8-tetrahydronaphthalenes.
