77902-90-0

Basic information

• Product Name: ETHYL L-2-((TRIFLUOROMETHYLSULFONYL)OXY)PROPIONATE
• Synonyms: ETHYL L-2-((TRIFLUOROMETHYLSULFONYL)OXY)PROPIONATE
• CAS NO: 77902-90-0
• Molecular Formula: C₆H₉F₃O₅S
• Molecular Weight: 0
• Mol File: 77902-90-0.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: ETHYL L-2-((TRIFLUOROMETHYLSULFONYL)OXY)PROPIONATE(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL L-2-((TRIFLUOROMETHYLSULFONYL)OXY)PROPIONATE(77902-90-0)
• EPA Substance Registry System: ETHYL L-2-((TRIFLUOROMETHYLSULFONYL)OXY)PROPIONATE(77902-90-0)

Safety Data

• Hazardous Substances Data: 77902-90-0(Hazardous Substances Data)

Upstream product

• 97-64-3 ethyl 2-hydroxypropionate 
• 358-23-6 trifluoromethylsulfonic anhydride 

Downstream Products

• 103954-36-5 (2S,1'S)-N⁶-<1-(Ethoxycarbonyl)ethyl>lysin-methylester 
• 103954-34-3 (2S,1'R)-N⁶-<1-(Ethoxycarbonyl)ethyl>lysin-methylester 
• 1006904-68-2 ethyl-2-(trifluoromethoxy)propanoate 
• 349-43-9 ethyl 2-fluoropropionate 
• 1122-43-6 2,6-dimethyl-3-hydroxypyridine 
• 88912-03-2 ethyl 2-phenylaminopropionate 
• 1435462-70-6 ethyl N-(2-chloro-5-nitropyrimidin-4-yl)-N-phenylalaninate 
• 33318-76-2 2-phenyl-4-methyl-5-ethoxy-1,3-oxazole 
• 1401015-52-8 2-n-propyl-4-methyl-5-ethoxy-1,3-oxazole 
• 68484-91-3 2-benzyl-4-methyl-5-ethoxy-1,3-oxazole 
• 1357010-68-4 1-tert-butyl 4-ethyl 2-(2-benzyloxycarbonylamino-3-ethylpentanoyl)-3-methylsuccinate 
• 52750-05-7 ethyl (E)-3-(4-methoxyphenyl)-2-methylpropenoate 
• 92576-43-7 ethyl 3-(4-chlorophenyl)-2-methyl-2-propenoate 
• 7042-33-3 ethyl (E)-2-methyl-3-phenyl-2-propenoate 

Relevant articles and documents

New chiral imidazolium ionic liquids: 3D-network of hydrogen bonding

New hydrophobic chiral ionic liquids bearing an imidazolium core have been stereospecifically prepared from the chiral pool; their enantiomeric purity and 3D-network of hydrogen bonding were analysed by NMR and X-ray diffraction, respectively.

DIHYDROPTERIDINONES

Compounds of Formula I, as shown below and defined herein: pharmaceutically acceptable salts thereof, synthesis, intermediates, formulations, and methods of disease treatment therewith, including treatment of cancers, such as tumors driven or mediated at

Nucleophilic fluorination of triflates by tetrabutylammonium bifluoride

(Chemical Equation Presented) Careful examination of nucleophilicity, basicity, and leaving group ability led us to discover the nucleophilic fluorination of triflates by weakly basic tetrabutylammonium bifluoride, which provides excellent yields with minimal formation of elimination-derived side products. Primary hydroxyl groups as well as secondary hydroxyl groups in acyclic chains or in five-membered rings are excellent substrates, whereas benzylic and aldol-type secondary hydroxyl groups give poor yields as a result of the instability of their triflates.