779335-37-4

Upstream product

• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 3095-95-2 diethylphosphonoacetic acid 
• 758640-21-0 N-Benzylaniline 
• 52190-13-3 N-benzyl-2-bromo-N-phenylacetamide 
• 122-52-1 triethyl phosphite 
• 34170-81-5 diethyl (2-chloro-2-oxoethyl)phosphonate 

Downstream Products

• 71687-77-9 (Z)-1-benzyl-3-benzylidene-1,3-dihydro-indol-2-one 
• 71687-76-8 (E)-1-benzyl-3-benzylidene-1,3-dihydro-indol-2-one 
• 847437-08-5 diethyl (1-benzyl-2-oxoindolin-3-yl)phosphonate 
• 119288-67-4 diethyl (+/-)-trans-1,4-diphenyl-2-oxo-azetidin-3-yl-phosphonate 
• 847437-06-3 [(benzyl-phenyl-carbamoyl)-diazo-methyl]-phosphonic acid diethyl ester 
• 779335-44-3 [(benzyl-phenyl-carbamoyl)-(2,2,6,6-tetramethyl-piperidin-1-yloxy)-methyl]-phosphonic acid diethyl ester 

Relevant academic research and scientific papers

Rh(II)-catalyzed intramolecular C-H insertion of diazo substrates in water: Scope and limitations

Preferential Rh(II) carbenoid intramolecular C-H versus O-H insertion derived from α-diazo-acetamides can be achieved in water by using an appropriate combination of the catalyst and amide groups, which creates a larger hydrophobic environment around the

One-pot homolytic aromatic substitutions/HWE olefinations under microwave conditions for the formation of a small oxindole library

(Chemical Equation Presented) An efficient one-pot sequence comprising a homolytic aromatic substitution followed by an ionic Horner Wadsworth-Emmons olefination for the preparation of a small library of α,β-unsaturated oxindoles is presented. Microwave-induced heating is used to conduct these reactions. The homolytic aromatic substitution is mediated by the persistent radical effect.