779357-96-9Relevant academic research and scientific papers
Titanium-mediated domino radical cyclization/βelimination of phosphine oxides
Leca, Dominique,Fensterbank, Louis,Lacote, Emmanuel,Malacria, Max
, p. 4220 - 4222 (2004)
A phosphinoyl radical leaving group in the β position is a key feature of a new TiIII,-mediated domino radical cyclization/β elimination reaction of vinylic phosphine oxides, which affords alkylidene-pyrrolidines in good yields (see scheme).
Titanocene-mediated intramolecular radical vinylations
Leca, Dominique,Song, Kai,Albert, Matthias,Goncalves, Monica Grangeio,Fensterbank, Louis,Lacote, Emmanuel,Malacria, Max
, p. 1405 - 1420 (2007/10/03)
A new titanium-mediated domino intramolecular radical vinylation is described. It relies on the radical β-elimination of sulfoximyl and phosphinoyl radicals, and leads efficiently to exo-alkylidene pyrrolidines with one stereogenic center β to the nitroge
